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Electronic ground s...
Electronic ground state of Ni 2 +
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- Zamudio-Bayer, V. (författare)
- Helmholtz Association of German Research Centers,Albert-Ludwigs University Freiburg
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- Lindblad, R. (författare)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Helmholtz Association of German Research Centers
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- Bülow, C. (författare)
- Helmholtz Association of German Research Centers
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- Leistner, G. (författare)
- Helmholtz Association of German Research Centers
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- Terasaki, A. (författare)
- Toyota Technological Institute
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- Issendorff, B. V. (författare)
- Albert-Ludwigs University Freiburg
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- Lau, J. T. (författare)
- Helmholtz Association of German Research Centers
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(creator_code:org_t)
- AIP Publishing, 2016
- 2016
- Engelska.
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Ingår i: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 145:19
- Relaterad länk:
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http://dx.doi.org/10...
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http://arxiv.org/pdf...
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The Φ9/24 ground state of the Ni2+ diatomic molecular cation is determined experimentally from temperature and magnetic-field-dependent x-ray magnetic circular dichroism spectroscopy in a cryogenic ion trap, where an electronic and rotational temperature of 7.4±0.2 K was reached by buffer gas cooling of the molecular ion. The contribution of the spin dipole operator to the x-ray magnetic circular dichroism spin sum rule amounts to 7Tz=0.17±0.06μB per atom, approximately 11% of the spin magnetic moment. We find that, in general, homonuclear diatomic molecular cations of 3d transition metals seem to adopt maximum spin magnetic moments in their electronic ground states.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
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