Real time observation of ultrathin epitaxial oxide growth during alloy oxidation

We have studied the thermal oxidation of the intermetallic alloy CoGa in situ, in real time on the atomic scale, during the growth of an ultrathin, epitaxial Ga oxide layer. On the basis of an extended set of surface x-ray diffraction data, density functional theory calculations and core level spectroscopy data, we find that the oxide film consists of an oxygen ion double layer, which contains the basic building block of bulk beta- Ga2O3. The oxide formation takes place via the nucleation of two- dimensional, anisotropic oxide islands which laterally grow and coalesce. A dramatic increase of the oxide island size is observed for low O-2 pressures in the 10(-8) mbar regime, which we interpret as the onset of a step flow like growth mode. This allows us to conclude that thermal oxidation can be considered as a hetero- epitaxial growth process, that follows similar atomistic growth principles to molecular beam epitaxy. As a consequence, the structural perfection of the oxide layer can be tailored by the appropriate choice of oxygen pressure and temperature.

Streitel, R. (författare)
Nolte, P. (författare)
Vlad, A. (författare)
Costina, I. (författare)
Marsman, M. (författare)
Kresse, G. (författare)
Lundgren, EdvinLund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)slju-elu (författare)
Andersen, Jesper NLund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)slju-jan (författare)
Franchy, R. (författare)
Dosch, H. (författare)
SynkrotronljusfysikFysiska institutionen (creator_code:org_t)

Av författaren/redakt...: Stierle, A.; Streitel, R.; Nolte, P.; Vlad, A.; Costina, I.; Marsman, M.; visa fler...; Kresse, G.; Lundgren, Edvin; Andersen, Jesper ...; Franchy, R.; Dosch, H.; visa färre...

Om ämnet

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.