WFRF:(Hübner Julia Maria)
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- Freccero, RiccardoUniversity of Genoa (author)
New Insights into the Crystal Chemistry of FeB-Type Compounds : The Case of CeGe
- Article/chapterEnglish2022
Publisher, publication year, extent ...
- 2022-12-19
- MDPI AG,2022
Numbers
- LIBRIS-ID:oai:lup.lub.lu.se:4a7ea736-8259-42b9-b96d-3aea59e0e4bb
- https://lup.lub.lu.se/record/4a7ea736-8259-42b9-b96d-3aea59e0e4bbURI
- https://doi.org/10.3390/ma15249089DOI
Supplementary language notes
- Language:English
- Summary in:English
Part of subdatabase
- SwePubSwePub
Classification
Notes
- Several alkaline earth or rare earth binary monosilicides and -germanides possess complex bonding properties, such as polycation formation exceeding the scope of classical electron counting rules. In this study, we present characterization by powder and single-crystal diffraction and thermal analysis of CeGe, one of the few monogermanides crystallizing in the FeB-type structure. Comparative computational investigations for structure types experimentally observed for monogermanides and alternative structures with different structural motifs were performed to gain energetical insights into this family of compounds, underlining the preference for infinite germanium chains over other structural motifs. Formation enthalpy calculations and structural chemical analysis highlight the special position of FeB-type compounds among the monogermanides.
Subject headings and genre
- NATURVETENSKAP Kemi Oorganisk kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Inorganic Chemistry hsv//eng
- chemical bonding
- crystal chemistry
- intermetallic compounds
- X-ray diffraction
Added entries (persons, corporate bodies, meetings, titles ...)
- Frick, EmmelinaLund University (author)
- Wilthorn, CarolineLund University (author)
- Hübner, Julia MariaLund University,Lunds universitet,NanoLund: Centre for Nanoscience,Annan verksamhet, LTH,Lunds Tekniska Högskola,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,LTH profilområde: Nanovetenskap och halvledarteknologi,LTH profilområden,Other operations, LTH,Faculty of Engineering, LTH,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,LTH Profile Area: Nanoscience and Semiconductor Technology,LTH Profile areas,Faculty of Engineering, LTH(Swepub:lu)ju7241hu (author)
- University of GenoaLund University (creator_code:org_t)
Related titles
- In:Materials: MDPI AG15:241996-1944
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