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Nuclear motion driven by the Renner-Teller effect as observed in the resonant Auger decay to the X̃2Π electronic ground state of N2O+

Miron, C. (author)
Saclay Nuclear Research Centre (CEA Saclay),University of Paris-Saclay
Simon, M. (author)
University of Paris-Saclay,Saclay Nuclear Research Centre (CEA Saclay)
Morin, P. (author)
University of Paris-Saclay,Saclay Nuclear Research Centre (CEA Saclay)
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Nanbu, S. (author)
Institute for Molecular Science
Kosugi, N. (author)
Institute for Molecular Science
Sorensen, S. L. (author)
Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
Naves De Brito, A. (author)
Brazilian Synchroton Light Laboratory
Piancastelli, M. N. (author)
University of Rome Tor Vergata
Björneholm, O. (author)
Uppsala University
Feifel, R. (author)
Uppsala University
Bässler, M. (author)
Uppsala University
Svensson, S. (author)
Uppsala University
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 (creator_code:org_t)
AIP Publishing, 2001
2001
English 6 s.
In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 115:2, s. 864-869
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The nuclear dynamics in the Nt 1s→π* in nitrous oxide was studied using the high resolution resonant Auger spectroscopy and ab initio quantum chemical calculations. For probing the nuclear motion of the system in the core-excited state, the frequency detuning technique was used. The results showed changes in vibrational structure for the Auger decay spectra and a strong influence of nuclear motion on the electronic decay.

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