Sökning: id:"swepub:oai:lup.lub.lu.se:7eb0f8c6-96c3-4fb8-ab8a-f48e5bd3f981" >
Chiral hexarhodium ...
Chiral hexarhodium clusters containing heterobidentate phosphine ligands, a structural and reactivity study
- Artikel/kapitelEngelska2003
Förlag, utgivningsår, omfång ...
-
2003
-
Royal Society of Chemistry (RSC),2003
Nummerbeteckningar
-
LIBRIS-ID:oai:lup.lub.lu.se:7eb0f8c6-96c3-4fb8-ab8a-f48e5bd3f981
-
https://lup.lub.lu.se/record/128391URI
-
https://doi.org/10.1039/b300951cDOI
Kompletterande språkuppgifter
-
Språk:engelska
-
Sammanfattning på:engelska
Ingår i deldatabas
Klassifikation
-
Ämneskategori:art swepub-publicationtype
-
Ämneskategori:ref swepub-contenttype
Anmärkningar
-
Some intrinsically chiral [Rh6(CO)14(µ,2-PX)] clusters have been synthesized, beginning with reactions of [Rh6(CO)16–x(NCMe)x](x= 1, 2) with PX, where PX represents the bidentate bridging ligands diphenyl(benzothienyl)phosphine (1), diphenyl(2-thienyl)phosphine (2), di(2-thienyl)phenylphosphine (3), tris(2-thienyl)phosphine (4), diphenyl(2-pyridyl)phosphine (5) and diphenylvinylphosphine (6). The ligand tris(2-furyl)phosphine (7) shows no bridging capability. When x= 1 the initial products are the clusters [Rh6(CO)15(1-PX)] which undergo spontaneous CO loss to form [Rh6(CO)14(µ,2-PX)]. The structures of the [Rh6(CO)15(1-PX)] clusters have been elucidated by IR, NMR spectroscopy and FAB-MS spectrometry, and have been found to involve phosphorus atom coordination to a rhodium atom. In addition, the solid state structures of the [Rh6(CO)14(µ,2-Ph2P(2-benzothienyl))](8), [Rh6(CO)14(µ,2-Ph2P(2-thienyl))](9), [Rh6(CO)14(µ,2-PhP(2-thienyl)2)](10) and [Rh6(CO)14(µ,2-Ph2P(pyridyl))](12) clusters have been determined by X-ray crystallography. The various types of chirality exhibited by these clusters are discussed. A simple model is proposed to account for the ratios of stereochemical isomers found in the Rh6(CO)14(µ,2-PhP(2-thienyl)2 cluster. The kinetics of formation of the bridged clusters from the monosubstituted [Rh6(CO)15(1-PX)] clusters have been studied.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
-
Koshevoy, I O
(författare)
-
Poe, A J
(författare)
-
Farrar, D H
(författare)
-
Nordlander, EbbeLund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)ook1-eno
(författare)
-
Pakkanen, T A
(författare)
-
Haukka, M
(författare)
-
Kemiska institutionenInstitutioner vid LTH
(creator_code:org_t)
Sammanhörande titlar
-
Ingår i:Dalton Transactions: Royal Society of Chemistry (RSC):12, s. 2457-24671477-9234
-
Ingår i:Dalton Trans.: Royal Society of Chemistry (RSC):12, s. 2457-24671477-9226
Internetlänk
Hitta via bibliotek
Till lärosätets databas