Lifetime measurements of the e1II, v = 0 and v = 1 states of12C16O, 13C16O, and13C18O

• In a laboratory investigation using tunable picosecond lasers in a pump-probe configuration, lifetimes of the E 1u, v = 0 and v = 1 states of CO are experimentally determined. For E 'D, v = 1, the lifetime is found to vary significantly for the isotopomers. Combining the data with existing oscillator strengths, predissociation probabilities within the range of 93.6%-98.6% result for 12C16O, 13C16O, and 13C18O in the case of the E 1u, v = I state, which is the state that predominantly influences the isotopic fractionation of CO in interstellar clouds.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

Keyword

ISM: molecules

Molecular data

Techniques: spectroscopic

Publication and Content Type

art (subject category)

ref (subject category)