Methyl-3-hexenoate combustion chemistry : Experimental study and numerical kinetic simulation

Gerasimov, Ilya E.Voevodsky Institute of Chemical Kinetics and Combustion (författare)

This work represents a detailed investigation of combustion and oxidation of methyl-3-hexenoate (CAS Number 2396-78-3), including experimental studies of combustion and oxidation characteristics, quantum chemistry calculations and kinetic model refinement. Following experiments have been carried out: Speciation measurements during oxidation in a jet-stirred reactor at 1 atm; chemical speciation measurements in a stoichiometric premixed flame at 1 atm using molecular-beam mass-spectrometry; ignition delay times measurements in a shock tube at 20 and 40 bar; and laminar burning velocity measurements at 1 atm using a heat-flux burner over a range of equivalence ratios. An updated detailed chemical kinetic mechanism for methyl-3-hexenoate combustion based on previous studies was proposed and validated against the novel experimental data and the relevant data available in literature with satisfactory agreement. Sensitivity and reaction pathway analyses were performed to show main decomposition pathways of methyl-3-hexenoate and underline possible sources of disagreements between experiments and simulations.

Knyazkov, Denis A.Voevodsky Institute of Chemical Kinetics and Combustion (författare)
Bolshova, Tatyana A.Voevodsky Institute of Chemical Kinetics and Combustion (författare)
Shmakov, Andrey G.Voevodsky Institute of Chemical Kinetics and Combustion (författare)
Korobeinichev, Oleg P.Voevodsky Institute of Chemical Kinetics and Combustion (författare)
Carbonnier, MaximeUniversity of Burgundy (författare)
Lefort, BenoîteUniversity of Burgundy (författare)
Kéromnès, AlanUniversity of Burgundy (författare)
Le Moyne, LuisUniversity of Burgundy (författare)
Lubrano Lavadera, MarcoLund University,Lunds universitet,Förbränningsfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Combustion Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)ma2172lu (författare)
Konnov, Alexander A.Lund University,Lunds universitet,Förbränningsfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Combustion Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)forb-aek (författare)
Zhou, Chong WenBeihang University (författare)
Serinyel, ZeynepUniversity of Orléans (författare)
Dayma, GuillaumeUniversity of Orléans (författare)
Dagaut, PhilippeInstitut de Combustion, Aérothermique, Réactivité et Environnement (författare)
Voevodsky Institute of Chemical Kinetics and CombustionUniversity of Burgundy (creator_code:org_t)

Av författaren/redakt...: Gerasimov, Ilya ...; Knyazkov, Denis ...; Bolshova, Tatyan ...; Shmakov, Andrey ...; Korobeinichev, O ...; Carbonnier, Maxi ...; visa fler...; Lefort, Benoîte; Kéromnès, Alan; Le Moyne, Luis; Lubrano Lavadera ...; Konnov, Alexande ...; Zhou, Chong Wen; Serinyel, Zeynep; Dayma, Guillaume; Dagaut, Philippe; visa färre...

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