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Automatic generatio...
Automatic generation of a detailed mechanism for the oxidation of n-decane
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- Moréac, Gladys (författare)
- Lund University,Lunds universitet,Förbränningsfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Combustion Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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- Blurock, Edward (författare)
- Lund University,Lunds universitet,Förbränningsfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Combustion Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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- Mauss, Fabian (författare)
- Lund University,Lunds universitet,Förbränningsfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Combustion Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
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(creator_code:org_t)
- 2006-09-21
- 2006
- Engelska.
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Ingår i: Combustion Science and Technology. - : Informa UK Limited. - 1563-521X .- 0010-2202. ; 178:10-11, s. 2025-2038
- Relaterad länk:
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http://dx.doi.org/10...
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visa fler...
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- A single detailed kinetic mechanism for the oxidation and combustion of n-decane and n-heptane has been written by means of an automatic mechanism generator ( REACTION) developed in our laboratory. It shows a good prediction of the ignition delay time versus temperature for the oxidation of n-decane at 13 and 50 bar and n-heptane at 13 and 40 bar for different equivalence ratios. The n-decane/n-heptane mechanism consists of a validated and recently published O-2=H-2=C-1-C-4 mechanism produced manually and a generated C-5-C-10 set of sub-mechanisms. The mechanism includes a complete description of both n-decane and n-heptane chemistry. This mechanism has a reasonable size, 506 species and 3684 reactions, but nevertheless it has an extensive range of chemistry. This paper represents not only the validation of a specific mechanism but also a validation of the rate constants of the reaction classes used to model the oxidation of alkanes at low and high temperature.
Ämnesord
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Nyckelord
- n-heptane
- n-decane
- mechanism
- combustion
- kinetics
- oxidation
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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