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- Karpenko, A. (author)
Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization
- Article/chapterEnglish2014
Publisher, publication year, extent ...
- AIP Publishing,2014
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- LIBRIS-ID:oai:lup.lub.lu.se:b98c3a42-ac86-4cee-9df0-19ee202ccaa1
- https://lup.lub.lu.se/record/4552636URI
- https://doi.org/10.1063/1.4880120DOI
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- Language:English
- Summary in:English
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Notes
- The inner-valence region of alkali bromide XBr (X=Li, Na, K, Rb) vapours has been studied experimentally by means of synchrotron radiation excited photoelectron spectroscopy. Experimental spectra were analyzed by comparing them with available theoretical results and previous experiments. Ionic character of alkali bromides is seen to change in the inner-valence region with increasing atomic number of the alkali atom. A mechanism involving mixing between Br 4s and Rb 4p orbitals has been suggested to account for the fine structure observed in inner-valence ionization region of RbBr. (C) 2014 AIP Publishing LLC.
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- NATURVETENSKAP Fysik hsv//swe
- NATURAL SCIENCES Physical Sciences hsv//eng
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- Iablonskyi, D. (author)
- Urpelainen, SamuliLund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory(Swepub:lu)maxl-sua (author)
- Kettunen, J. A. (author)
- Cao, W. (author)
- Huttula, M. (author)
- Aksela, H. (author)
- Lunds universitetMAX IV-laboratoriet (creator_code:org_t)
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- In:Journal of Chemical Physics: AIP Publishing140:200021-96061089-7690
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