id:"swepub:oai:lup.lub.lu.se:de62cb7e-a5ab-4a33-88d1-a6aed2ae2f01"
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- Olsson, RogerLund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH (author)
Is a hydrogen bonded carbene an intermediate in the organoaluminum-induced ring opening of pyranosides?
- Article/chapterEnglish1997
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- 1997
- 4 s.
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- LIBRIS-ID:oai:lup.lub.lu.se:de62cb7e-a5ab-4a33-88d1-a6aed2ae2f01
- https://lup.lub.lu.se/record/de62cb7e-a5ab-4a33-88d1-a6aed2ae2f01URI
- https://doi.org/10.1016/S0040-4039(97)01250-1DOI
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- Language:English
- Summary in:English
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- Semiempirical and ab initio quantum chemical computations indicate that the intermediate formed prior to the selectivity-determining methyl transfer step in the reaction between glycosides and trimethylaluminum is a strongly hydrogen-bended equilibrium OH...C = O-H...C, which is proposed to be an important selectivity promoting factor in the alkyl transfer reaction.
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- Berg, UlfLund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)orgk1-ub (author)
- Frejd, TorbjörnLund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)orgk1-tf (author)
- Kemiska institutionenInstitutioner vid LTH (creator_code:org_t)
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- In:Tetrahedron Letters38:32, s. 5701-57040040-4039
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