Search: id:"swepub:oai:lup.lub.lu.se:de62cb7e-a5ab-4a33-88d1-a6aed2ae2f01" >
Is a hydrogen bonde...
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Olsson, RogerLund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
(author)
Is a hydrogen bonded carbene an intermediate in the organoaluminum-induced ring opening of pyranosides?
- Article/chapterEnglish1997
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LIBRIS-ID:oai:lup.lub.lu.se:de62cb7e-a5ab-4a33-88d1-a6aed2ae2f01
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https://lup.lub.lu.se/record/de62cb7e-a5ab-4a33-88d1-a6aed2ae2f01URI
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https://doi.org/10.1016/S0040-4039(97)01250-1DOI
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Language:English
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Summary in:English
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Subject category:art swepub-publicationtype
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Subject category:ref swepub-contenttype
Notes
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Semiempirical and ab initio quantum chemical computations indicate that the intermediate formed prior to the selectivity-determining methyl transfer step in the reaction between glycosides and trimethylaluminum is a strongly hydrogen-bended equilibrium OH...C = O-H...C, which is proposed to be an important selectivity promoting factor in the alkyl transfer reaction.
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Berg, UlfLund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)orgk1-ub
(author)
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Frejd, TorbjörnLund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)orgk1-tf
(author)
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Kemiska institutionenInstitutioner vid LTH
(creator_code:org_t)
Related titles
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In:Tetrahedron Letters38:32, s. 5701-57040040-4039
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