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Airborne Measurements of Ethene from Industrial Sources Using Laser Photo-Acoustic Spectroscopy

De Gouw, J. A. (author)
University of Colorado at Boulder,National Oceanic and Atmospheric Administration
Hekkert, S. T. L. (author)
Mellqvist, Johan, 1965 (author)
Chalmers tekniska högskola,Chalmers University of Technology
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Warneke, C. (author)
University of Colorado at Boulder,National Oceanic and Atmospheric Administration
Atlas, E. (author)
University of Miami
Fehsenfeld, F. C. (author)
University of Colorado at Boulder,National Oceanic and Atmospheric Administration
Fried, A. (author)
National Center for Atmospheric Research
Frost, G. J. (author)
National Oceanic and Atmospheric Administration,University of Colorado at Boulder
Harren, F. J. M. (author)
Radboud Universiteit,Radboud University
Holloway, J. S. (author)
University of Colorado at Boulder,National Oceanic and Atmospheric Administration
Lefer, B. (author)
University of Houston
Lueb, R. (author)
University of Miami
Meagher, J. F. (author)
National Oceanic and Atmospheric Administration
Parrish, D. D. (author)
National Oceanic and Atmospheric Administration
Patel, M. (author)
University of Houston
Pope, L. (author)
University of Miami
Richter, D. (author)
National Center for Atmospheric Research
Rivera, Claudia, 1976 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Ryerson, T. B. (author)
National Oceanic and Atmospheric Administration
Samuelsson, Jerker, 1972 (author)
Chalmers tekniska högskola,Chalmers University of Technology
Walega, J. G. (author)
National Center for Atmospheric Research
Washenfelder, R. A. (author)
National Oceanic and Atmospheric Administration,University of Colorado at Boulder
Weibring, P. (author)
National Center for Atmospheric Research
Zhu, X. (author)
University of Miami
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 (creator_code:org_t)
2009-03-09
2009
English.
In: Environmental Science & Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 43:7, s. 2437-2442
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • A laser photoacoustic spectroscopy (LPAS) instrument was developed and used for aircraft measurements of ethene from industrial sources near Houston, Texas. The instrument provided 20 s measurements with a detection limit of less than 0.7 ppbv. Data from this instrument and from the GC-FID analysis of air samples collected in flight agreed within 15% on average. Ethene fluxes from the Mt. Belvieu chemical complex to the northeast of Houston were quantified during 10 different flights. The average flux was 520 +/- 140 kg h(-1) in agreement with independent results from solar occultation flux (SOF) measurements, and roughly an order of magnitude higher than regulatory emission inventories indicate. This study shows that ethene emissions are routinely at levels that qualify as emission upsets, which need to be reported to regional air quality managers.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Naturresursteknik -- Annan naturresursteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Environmental Engineering -- Other Environmental Engineering (hsv//eng)

Keyword

texas
emissions
organic-compounds
ozone formation
houston

Publication and Content Type

art (subject category)
ref (subject category)

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