Search: WFRF:(Jonsson Erlendur 1983) >
Towards standard el...
-
Monti, Damien,1986Chalmers tekniska högskola,Chalmers University of Technology,Institut de Ciència de Materials de Barcelona (ICMAB-CSIC),Institute of Material Science of Barcelona (ICMAB),Centre national de la recherche scientifique (CNRS)
(author)
Towards standard electrolytes for sodium-ion batteries: physical properties, ion solvation and ion-pairing in alkyl carbonate solvents
- Article/chapterEnglish2020
Publisher, publication year, extent ...
-
2020
-
Royal Society of Chemistry (RSC),2020
-
electronicrdacarrier
Numbers
-
LIBRIS-ID:oai:research.chalmers.se:16b15608-e82e-48dd-af1f-32d261a528b3
-
https://doi.org/10.1039/d0cp03639kDOI
-
https://research.chalmers.se/publication/520286URI
Supplementary language notes
-
Language:English
-
Summary in:English
Part of subdatabase
Classification
-
Subject category:art swepub-publicationtype
-
Subject category:ref swepub-contenttype
Notes
-
The currently emerging sodium-ion battery technology is in need of an optimized standard organic solvent electrolyte based on solid and directly comparable data. With this aim we have made a systematic study of "simple"electrolyte systems consisting of two sodium salts (NaTFSI and NaPF6) dissolved in three different alkyl carbonate solvents (EC, PC, DMC) within a wide range of salt concentrations and investigated: (i) their more macroscopic physico-chemical properties such as ionic conductivity, viscosity, thermal stability, and (ii) the molecular level properties such as ion-pairing and solvation. From this all electrolytes were found to have useful thermal operational windows and electrochemical stability windows, allowing for large scale energy storage technologies focused on load levelling or (to a less extent) electric vehicles, and ionic conductivities on par with analogous lithium-ion battery electrolytes, giving promise to also be power performant. Furthermore, at the molecular level the NaPF6-based electrolytes are more dissociated than the NaTFSI-based ones because of the higher ionic association strength of TFSI compared to PF6- while two different conformers of DMC participate in the Na+ first solvation shells-a Na+ affected conformational equilibrium and induced polarity of DMC. The non-negligible presence of DMC in the Na+ first solvation shells increases as a function of salt concentration. Overall, these results should both have a general impact on the design of more performant Na-conducting electrolytes and provide useful insight on the very details of the importance of DMC conformers in any cation solvation studies.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
-
Jonsson, Erlendur,1983Chalmers tekniska högskola,Chalmers University of Technology,University Of Cambridge(Swepub:cth)erlendur
(author)
-
Boschin, Andrea,1981Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)andbos
(author)
-
Palacin, M. R.Institut de Ciència de Materials de Barcelona (ICMAB-CSIC),Institute of Material Science of Barcelona (ICMAB),Centre national de la recherche scientifique (CNRS)
(author)
-
Ponrouch, A.Institut de Ciència de Materials de Barcelona (ICMAB-CSIC),Institute of Material Science of Barcelona (ICMAB),Centre national de la recherche scientifique (CNRS)
(author)
-
Johansson, Patrik,1969Centre national de la recherche scientifique (CNRS),Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)jpatrik
(author)
-
Chalmers tekniska högskolaInstitut de Ciència de Materials de Barcelona (ICMAB-CSIC)
(creator_code:org_t)
Related titles
-
In:Physical Chemistry Chemical Physics: Royal Society of Chemistry (RSC)22:39, s. 22768-227771463-90841463-9076
Internet link
Find in a library
To the university's database