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In Situ Plasmonic N...
In Situ Plasmonic Nanospectroscopy of the CO Oxidation Reaction over Single Pt Nanoparticles
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- Liu, Su, 1983 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Susarrey- Arce, Arturo, 1981 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Nilsson, Sara, 1990 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Albinsson, David, 1990 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Hellberg, Lars, 1960 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Alekseeva, Svetlana, 1987 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Langhammer, Christoph, 1978 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- 2019-05-15
- 2019
- Engelska.
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Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-086X .- 1936-0851. ; 13:5, s. 6090-6100
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https://pubs.acs.org...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The ongoing quest to develop single-particle methods for the in situ study of heterogeneous catalysts is driven by the fact that heterogeneity in terms of size, shape, grain structure, and composition is a general feature among nanoparticles in an ensemble. This heterogeneity hampers the generation of a deeper understanding for how these parameters affect catalytic properties. Here we present a solution that in a single benchtop experimental setup combines single-particle plasmonic nanospectroscopy with mass spectrometry for gas phase catalysis under reaction conditions at high temperature. We measure changes in the surface state of polycrystalline platinum model catalyst particles in the 70 nm size range and the corresponding bistable kinetics during the carbon monoxide oxidation reaction via the peak shift of the dark-field scattering spectrum of a closely adjacent plasmonic nanoantenna sensor and compare these changes with the total reaction rate measured by the mass spectrometer from an ensemble of nominally identical particles. We find that the reaction kinetics of simultaneously measured individual Pt model catalysts are dictated by the grain structure and that the superposition of the individual nanoparticle response can account for the significant broadening observed in the corresponding nanoparticle ensemble data. In a wider perspective our work enables in situ plasmonic nanospectroscopy in controlled gas environments at high temperature to investigate the role of the surface state on transition metal catalysts during reaction and of processes such as alloying or surface segregation in situ at the single-nanoparticle level for model catalysts in the few tens to hundreds of nanometer size range.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Annan kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
- NATURVETENSKAP -- Fysik -- Annan fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Other Physics Topics (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Metallurgi och metalliska material (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Metallurgy and Metallic Materials (hsv//eng)
Nyckelord
- single particle
- CO oxidation
- bistable kinetics
- single-particle catalysis
- dark-field scattering spectroscopy
- plasmonic nanospectroscopy
- quadrupole mass spectrometry
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ACS Nano
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- Av författaren/redakt...
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Liu, Su, 1983
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Susarrey- Arce, ...
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Nilsson, Sara, 1 ...
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Albinsson, David ...
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Hellberg, Lars, ...
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Alekseeva, Svetl ...
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Langhammer, Chri ...
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- TEKNIK OCH TEKNOLOGIER
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TEKNIK OCH TEKNO ...
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och Kemiteknik
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och Annan kemiteknik
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- NATURVETENSKAP
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NATURVETENSKAP
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och Fysik
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och Annan fysik
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- TEKNIK OCH TEKNOLOGIER
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TEKNIK OCH TEKNO ...
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och Materialteknik
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och Metallurgi och m ...
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ACS Nano
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Chalmers tekniska högskola