Formation of small lanthanum-carbide ions from laser induced fragmentation of La@C-82

• The fragmentation behavior of the endohedral metallofullerene La@C-82 was studied using gas phase time-of-flight mass spectrometry. The results were compared with the fragmentation of C-60. When the metallofullerene was excited by a 337 nm ns laser, small lanthanum-carbide fragments LaCn+, n=0-6, were detected. A simple statistical maximum entropy model was used to simulate the excitation energy dependence of the loss of the LaCn+ molecules as well as C-2 evaporation to form smaller metallofullerenes. By comparing experimental ion intensities with the model, the appearance energies of LaCn+, n=0-6, were found to lie above 65 eV. The lanthanum-carbide fragments ejected from La@C-82 decrease in size with increasing internal energy. The ejection of La+ and LaC2+ is preferred at the expense of larger fragments such as LaC4+ and metallofullerenes at the higher excitation. (C) 2003 American Institute of Physics.

Ämnesord

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

Nyckelord

CARBON

ENERGIES

CLUSTERS

IONIZATION

MASS-SPECTROMETRY

ENDOHEDRAL FULLERENES

DISSOCIATION

METALLOFULLERENES

ELECTRONIC-STRUCTURE

C-60

ENDOHEDRAL FULLERENES; ELECTRONIC-STRUCTURE; MASS-SPECTROMETRY; C-60; CLUSTERS; CARBON; METALLOFULLERENES; IONIZATION; DISSOCIATION; ENERGIES

Publikations- och innehållstyp

art (ämneskategori)

ref (ämneskategori)