Sökning: WFRF:(Jankowski Piotr 1990)
> Younesi Reza >
Prospects for Impro...
-
Jankowski, Piotr,1990Politechnika Warszawska,Warsaw University of Technology,Chalmers tekniska högskola,Chalmers University of Technology,Danmarks Tekniske Universitet,Technical University of Denmark,Alistore - European Research Institute,Chalmers Univ Technol, Dept Phys, S-41296 Gothenburg, Sweden.;Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland.;ALISTORE European Res Inst, CNRS FR 3104, Hub Energie, Rue Baudelocque, F-80039 Amiens, France.;Tech Univ Denmark, Dept Energy Convers & Storage, DK-2800 Lyngby, Denmark.
(författare)
Prospects for Improved Magnesocene-Based Magnesium Battery Electrolytes
- Artikel/kapitelEngelska2021
Förlag, utgivningsår, omfång ...
-
2021-05-05
-
Wiley,2021
-
electronicrdacarrier
Nummerbeteckningar
-
LIBRIS-ID:oai:research.chalmers.se:451c25dc-00c3-4675-bd58-14b17a47ec3c
-
https://doi.org/10.1002/batt.202100040DOI
-
https://research.chalmers.se/publication/524104URI
-
https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-454294URI
Kompletterande språkuppgifter
-
Språk:engelska
-
Sammanfattning på:engelska
Ingår i deldatabas
Klassifikation
-
Ämneskategori:art swepub-publicationtype
-
Ämneskategori:ref swepub-contenttype
Anmärkningar
-
Magnesium batteries are currently attracting a lot of interest as a next generation battery technology. One critical issue is to find a suitable electrolyte and herein we explore an electrolyte based on magnesocene (MgCp2) in tetrahydrofuran (THF), aiming for low-voltage Mg batteries, with respect to: Mg plating characteristics, electrochemical stability windows, electrolyte speciation, and electrolyte decomposition reactions; both experimentally and computationally. Overall, the electrolyte does not seem to decompose on a Mg metal anode and most likely reduced solvation of Mg2+ by the Cp- anion is important and species such as MgCp2THF2 may play an important role for Mg plating with small overpotential. The oxidation limit is largely determined by the Cp- anion and density functional theory predicted oxidation reactions point to polymerized end-products to be possible. Furthermore, in silico substitution studies enable us to establish the prospects of some Cp- anion derivatives to further improve the oxidative stability, but still the Mg2+ solvation must be monitored for ease of reduction and Mg plating.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
-
Schwarz, RainerZentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Wurttembergstiftung (ZSW),ZSW Zentrum Sonnenenergie & Wasserstoff, Forsch Baden Wurttemberg, D-89081 Ulm, Germany.
(författare)
-
Randon-Vitanova, AnnaHonda R&D Europe (Tyskland) GmbH,Honda R&D Europe (Germany) GmbH,Honda R&D Europe Deutschland GmbH, D-63073 Offenbach, Germany.
(författare)
-
Younesi, RezaUppsala universitet,Strukturkemi,ALISTORE European Res Inst, CNRS FR 3104, Hub Energie, Rue Baudelocque, F-80039 Amiens, France.(Swepub:uu)rezyo975
(författare)
-
Wachtler, MarioUppsala universitet,Strukturkemi,ZSW Zentrum Sonnenenergie & Wasserstoff, Forsch Baden Wurttemberg, D-89081 Ulm, Germany.(Swepub:uu)marwa112
(författare)
-
Johansson, Patrik,1969Alistore - European Research Institute,Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Dept Phys, S-41296 Gothenburg, Sweden.;ALISTORE European Res Inst, CNRS FR 3104, Hub Energie, Rue Baudelocque, F-80039 Amiens, France.(Swepub:cth)jpatrik
(författare)
-
Politechnika WarszawskaChalmers tekniska högskola
(creator_code:org_t)
Sammanhörande titlar
-
Ingår i:Batteries and Supercaps: Wiley4:8, s. 1335-13432566-6223
Internetlänk
Hitta via bibliotek
Till lärosätets databas