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Conduction mechanis...
Conduction mechanism in polymeric membranes based on PEO or PVdF-HFP and containing a piperidinium ionic liquid
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- Elamin, Khalid, 1977 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Shojaatalhoseini, Mansoureh, 1981 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Danyliv, Olesia, 1989 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Martinelli, Anna, 1978 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Swenson, Jan, 1966 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- Elsevier BV, 2019
- 2019
- Engelska.
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Ingår i: Electrochimica Acta. - : Elsevier BV. - 0013-4686. ; 299, s. 979-986
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https://doi.org/10.1...
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Abstract
Ämnesord
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- Two types of polymer electrolyte membranes were prepared using poly(ethylene oxide) (PEO) and poly(vinylidene difluoride-co-hexafluoropropylene) (PVdF-HFP), with different amounts of the ionic liquid N-methyl-N-propylpiperidinium bis(trifluoromethane-sulfonyl) imide ([PP13][TFSI]) added. The results from differential scanning calorimetry and conductivity measurements show that in the case of PVdF-HFP membranes the glass transition temperature T-g decreases and the room temperature ionic conductivity increases with increasing content of the ionic liquid (up to 60 wt.%). However, in the case of PEO based membranes Tg is less significantly affected and the room temperature ionic conductivity increases only up to 30 wt.% of ionic liquid, beyond which a steady value of about 5.10(-5) S/cm is reached. The results from Raman spectroscopy show that the characteristic vibrational mode of the TFSI anion at similar to 742 cm(-1) is weakly affected in the membranes prepared from PVdF-HFP, whereas for those based on PEO it has a clearer composition dependence. These results suggest ion-ion and ion-polymer interactions of different nature, which together with the different nanomorphologies adopted by PEO and PVdF-HFP, as revealed by X-ray scattering, give rise to different composition dependences of the macroscopically measured ionic conductivity. (C) 2019 The Authors. Published by Elsevier Ltd.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Keramteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Ceramics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- NATURVETENSKAP -- Fysik -- Annan fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Other Physics Topics (hsv//eng)
Nyckelord
- Ionic liquid and ionic conductivity
- Poly(vinylidene difluoride-co-hexafluoropropylene)
- Poly(ethylene oxide)
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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