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Influence of side c...
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Hellström, Stefan,1978Chalmers tekniska högskola,Chalmers University of Technology,Chalmers
(författare)
Influence of side chains on electrochromic properties of green donor-acceptor-donor polymers
- Artikel/kapitelEngelska2011
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Nummerbeteckningar
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LIBRIS-ID:oai:research.chalmers.se:58ac39f4-5c97-4eca-8356-64fb3fc33417
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https://research.chalmers.se/publication/140777URI
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https://doi.org/10.1016/j.electacta.2010.11.018DOI
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https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-68227URI
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Språk:engelska
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Sammanfattning på:engelska
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Klassifikation
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Ämneskategori:art swepub-publicationtype
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Ämneskategori:ref swepub-contenttype
Anmärkningar
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Three solution processable cathodically coloring green electrochromic polymers, based on 2,3-diphenyl-5,7-di(thiophen-2-yl)thieno[3,4-b]pyrazine, have been synthesized by oxidative FeCl3 polymerization. The polymers were designed with solubilizing alkyl and oligoethylene oxide side chains to achieve solubility and processability. All three polymers have a small electrochemical bandgap (1.8-1.9 eV) and low oxidation potentials. Spectroelectrochemical studies of polymer films on ITO reveal that the alkyl side chains in head-to-head position on the polymer backbone promote a defined high-energy absorption peak and suppress tailing of charge-carrier absorption into the visible region. Kinetic studies, based on transmission measurements applying a square-wave potential between reduced and oxidized states, show that the polymer with exclusively oligoethylene oxide side chains (P3) had the fastest response times, monitored at the low-energy absorption maxima. The best performing polymer (P1) showed a good optical contrast in the visible region with a Delta T of 26% at 700 nm. An initial test of the electrochemical stability showed that the oligoethylene oxide containing polymers had superior stability over 500 full switches.
Ämnesord och genrebeteckningar
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NATURVETENSKAP Kemi hsv//swe
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NATURAL SCIENCES Chemical Sciences hsv//eng
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Spectroelectrochemistry
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processable green
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solar-cells
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Conjugated polymer
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Electrochromism
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FeCl3-polymerization
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polymerization
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oxidized state
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distributions
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design
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maldi-ms
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neutral state
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copolymers
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realization
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MALDI-TOF
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TECHNOLOGY
Biuppslag (personer, institutioner, konferenser, titlar ...)
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Cai, TianqiChalmers tekniska högskola,Chalmers University of Technology,East China University of Science and Technology,Chalmers
(författare)
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Inganäs, OlleLinköpings universitet,Biomolekylär och Organisk Elektronik,Tekniska högskolan(Swepub:liu)ollin59
(författare)
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Andersson, Mats,1966Chalmers tekniska högskola,Chalmers University of Technology,Chalmers(Swepub:cth)matsand
(författare)
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Chalmers tekniska högskolaChalmers
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Electrochimica Acta: Elsevier BV56:10, s. 3454-34590013-4686
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