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- Mahmoudkhani, Amir H. (author)
Radical Additions of Bis(trimethylsilyl)phosphite to Vinyltrimethylsilane and Vinyltriethoxysilane: Crystal Structure of 2-Trimethylsilylethylphosphonic Acid
- Article/chapterEnglish2003
Publisher, publication year, extent ...
- 2010-10-27
- Informa UK Limited,2003
Numbers
- LIBRIS-ID:oai:research.chalmers.se:8b2c2533-8c8d-4d1a-94e1-58c546d64bc9
- https://doi.org/10.1080/713744570DOI
- https://research.chalmers.se/publication/3627URI
Supplementary language notes
- Language:English
- Summary in:English
Part of subdatabase
- SwePubSwePub
Classification
Notes
- Organosilicon-phosphonate compounds with the general formula (R)n(RO)3mnSi(CH2)mP(O)(OSiR'3)2 are designed for application as novel materials for surface treatments and modifications. A solvothermal method based on the reaction of bis(trimethylsilyl)phosphite with vinyltrimethylsilane and vinyltriethoxysilane in the presence of a peroxide in benzene solvent was used to synthesize the silyl-substituted esters of organosilicon-phosphonate compounds. 2-Trimethylsilylethanephosphonic acid was prepared from its bis(trimethylsilyl) ester by alcoholysis. The crystal structure of the acid consists of two-dimensional arrays built up from the (P--)O--H···O--P hydrogen bonds.
Subject headings and genre
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- Crystal Structure
- Surface Treatment
- Hydrogen Bonding
- Supramolecular Array
Added entries (persons, corporate bodies, meetings, titles ...)
- Langer, Vratislav,1949Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)langer (author)
- Lindqvist, Oliver,1943Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)oliver (author)
- Chalmers tekniska högskola (creator_code:org_t)
Related titles
- In:Phosphorus, Sulfur and Silicon and the Related Elements: Informa UK Limited178:10, s. 2159-21681042-65071563-5325
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