Search: WFRF:(Mårtensson Jerker 1965) >
Metal-Organic Frame...
-
Amombo Noa, Francoise Mystere,1988Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Dept Chem & Chem Engn, Chem & Biochem, SE-41296 Gothenburg, Sweden
(author)
Metal-Organic Frameworks with Hexakis(4-carboxyphenyl)benzene: Extensions to Reticular Chemistry and Introducing Foldable Nets
- Article/chapterEnglish2020
Publisher, publication year, extent ...
-
2020-04-21
-
American Chemical Society (ACS),2020
-
electronicrdacarrier
Numbers
-
LIBRIS-ID:oai:research.chalmers.se:8f54dfe6-94f8-4592-8d3f-e47aa38743c5
-
https://research.chalmers.se/publication/517520URI
-
https://doi.org/10.1021/jacs.0c02984DOI
-
https://research.chalmers.se/publication/517920URI
-
https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-182957URI
-
https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-415267URI
Supplementary language notes
-
Language:English
-
Summary in:English
Part of subdatabase
Classification
-
Subject category:art swepub-publicationtype
-
Subject category:ref swepub-contenttype
Notes
-
Nine metal-organic frameworks have been prepared with the hexagon-shaped linker 1,2,3,4,5,6-hexakis(4-carboxyphenyl)-benzene (H(6)cpb) by solvothermal reactions in dimethylformamide (dmf) or dimethylacetamide (dmac) with acetic acid or formic acid as modulators: [Bi-2(cpb)(acetato)(2)(dmf)(2)]center dot 2dmf CTH-6 forms a rtl-net; 2(H2NMe2)[Cu-2(cpb)] CTH-7 forms a kgd-net; [Fe-4(cpb)-(acetato)(2)(dmf)(4)] CTH-8 and [Co-4(cpb)(acetato)(2)(dmf)(4)] CTH-9 are isostructural and form yav-nets; 2(HNEt3)[Fe-2(cpb)] CTH-10 and the two polymorphs of 2(H2NMe2)[Zn-2(cpb)]center dot 1.5dmac, Zn-MOF-888 and CTH-11, show kgd-nets; [Cu-2(cpb)-(acetato)(2)(dmf)(2)]center dot 2dmf, CTH-12, forms a mixed coordination and hydrogen-bonded sql-net; and 2(H2NMe2)[Zn-2(cpb)] CTH-13, a similarly mixed yav-net. Surface area values (Brunauer-Emmett-Teller, BET) range from 34 m(2) g(-1) for CTH-12 to 303 m(2) g(-1) for CTH-9 for samples activated at 120 degrees C in dynamic vacuum. All compounds show normal (10-fold higher) molar CO2 versus N-2 uptake at 298 K, except the 19-fold CO2 uptake for CTH-12 containing Cu(II) dinuclear paddle-wheels. We also show how perfect hexagons and triangles can combine to a new 3D topology laf, a model of which gave us the idea of foldable network topologies, as the laf-net can fold into a 2D form while retaining the local geometry around each vertex. Other foldable nets identified are cds, cds-a, ths, sqc163, clh, jem, and tfc covering the basic polygons and their combinations. The impact of this concept on "breathing" MOFs is discussed. I-2 sorption, both from gas phase and from MeOH solution, into CTH-7 were studied by time of flight secondary ion mass spectrometry (ToF-SIMS) on dried crystals. I-2 was shown to have penetrated the crystals, as layers were consecutively peeled off by the ion beam. We suggest ToF-SIMS to be a method for studying sorption depth profiles of MOFs.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
-
Svensson Grape, ErikStockholms universitet,Institutionen för material- och miljökemi (MMK),Stockholm University,Stockholm Univ, Dept Mat & Environm Chem, SE-10691 Stockholm, Sweden(Swepub:su)ersv6431
(author)
-
Brülls, Steffen,1991Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Dept Chem & Chem Engn, Chem & Biochem, SE-41296 Gothenburg, Sweden(Swepub:cth)brullss
(author)
-
Cheung, OceanUppsala universitet,Nanoteknologi och funktionella material(Swepub:uu)ocech274
(author)
-
Malmberg, Per,1974Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Dept Chem & Chem Engn, Chem & Biochem, SE-41296 Gothenburg, Sweden(Swepub:cth)malmper
(author)
-
Inge, A. KenStockholms universitet,Institutionen för material- och miljökemi (MMK),Stockholm University,Stockholm Univ, Dept Mat & Environm Chem, SE-10691 Stockholm, Sweden(Swepub:su)ainge
(author)
-
McKenzie, Christine J.Syddansk Universitet,University of Southern Denmark,Univ Southern Denmark, Dept Phys Chem & Pharm, DK-5230 Odense M, Denmark
(author)
-
Mårtensson, Jerker,1965Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Dept Chem & Chem Engn, Chem & Biochem, SE-41296 Gothenburg, Sweden(Swepub:cth)jerker
(author)
-
Öhrström, Lars,1963Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Dept Chem & Chem Engn, Chem & Biochem, SE-41296 Gothenburg, Sweden(Swepub:cth)ohrstrom
(author)
-
Chalmers tekniska högskolaChalmers Univ Technol, Dept Chem & Chem Engn, Chem & Biochem, SE-41296 Gothenburg, Sweden
(creator_code:org_t)
Related titles
-
In:Journal of the American Chemical Society: American Chemical Society (ACS)142:20, s. 9471-94811520-51260002-7863
Internet link
Find in a library
To the university's database
- By the author/editor
-
Amombo Noa, Fran ...
-
Svensson Grape, ...
-
Brülls, Steffen, ...
-
Cheung, Ocean
-
Malmberg, Per, 1 ...
-
Inge, A. Ken
-
show more...
-
McKenzie, Christ ...
-
Mårtensson, Jerk ...
-
Öhrström, Lars, ...
-
show less...
- About the subject
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
-
and Physical Chemist ...
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
-
and Materials Chemis ...
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
- Articles in the publication
-
Journal of the A ...
- By the university
-
Chalmers University of Technology
-
Stockholm University
-
Uppsala University