WFRF:(Sillrén Per 1982)
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- Sillrén, Per,1982Chalmers tekniska högskola,Chalmers University of Technology (author)
Perturbation theory for systems with strong short-ranged interactions
- Article/chapterEnglish2007
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- 2007
- electronicrdacarrier
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- LIBRIS-ID:oai:research.chalmers.se:a42484fd-8f2f-4327-907f-abf07979c070
- https://research.chalmers.se/publication/68234URI
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- Language:English
- Summary in:English
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- We propose a variant of thermodynamic perturbation theory based on the Mayer f-function which is applicable to strongly repulsive, and even singular interactions. The expansion of the free energy is successfully tested against known 'exact results' for hard-sphere fluids, and then applied to binary mixtures of particles with non-additive hard cores or shouldered potentials. The resulting phase diagrams agree well with existing simulation data and theoretical predictions.
Subject headings and genre
- NATURVETENSKAP Fysik hsv//swe
- NATURAL SCIENCES Physical Sciences hsv//eng
- strong interactions
- hard sphere
- binary mixture
- statistical physics
- Perturbation theory
Added entries (persons, corporate bodies, meetings, titles ...)
- Hansen, Jean-Pierre,1942 (author)
- Chalmers tekniska högskola (creator_code:org_t)
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- In:Molecular Physics105:13-14, s. 1803-18111362-30280026-8976
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