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Morphology evolutio...
Morphology evolution of electrodeposited lithium on metal substrates
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- Jiao, Xingxing (author)
- Xi'an Jiaotong University
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- Wang, Yongjing (author)
- Xi'an Jiaotong University
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- Kapitanova, Olesya O. (author)
- Xi'an Jiaotong University
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- Xu, Xieyu (author)
- Xi'an Jiaotong University
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Volkov, Valentyn S. (author)
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- Liu, Yangyang (author)
- Xi'an Jiaotong University
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- Song, Zhongxiao (author)
- Xi'an Jiaotong University
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- Matic, Aleksandar, 1968 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Xiong, Shizhao, 1985 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- 2023
- 2023
- English.
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In: Energy Storage Materials. - 2405-8297. ; 61
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https://doi.org/10.1...
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Abstract
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- Lithium (Li) metal is deemed to be the high-energy-density anode material for next generation batteries, but its practical application is impeded by the uneven electrodeposition during charge of battery, which leads to the low Coulombic efficiency and potential safety issue. Here, multiscale modeling is fabricated to understand the morphology evolution of Li during electrodeposition process, from the self-diffusion of Li adatoms on electrode surface, to the nucleation process, and to the formation of Li microstructures, revealing the correlation between final morphology and deposition substrates. Energy batteries and self-diffusion of Li adatom on various substrates (lithium, copper, nickel, magnesium, and silver) result in the different nucleation size, which is calculated by kinetic Monte Carlo simulation based on classical nucleation theory. Formation of Li substructures that are grown from Li nuclei, is revealed by phase field modeling coupled with cellular automaton method. Our results show that larger Li nuclei is obtained under faster self-diffusion of Li adatom, leading to the low aspect ratio of Li substructures and the subsequent morphology evolution of electrodeposited Li. Furthermore, the electrodeposition of Li is strongly regulated by the selection of substrates, giving the practical guideline of anode design in rechargeable Li metal batteries. It is worthy to mention that this method to investigate the electro-crystallization process involving nucleation and growth can be transplanted to the other metallic anode, such as sodium, potassium, zinc, magnesium, calcium and the like.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Bearbetnings-, yt- och fogningsteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Manufacturing, Surface and Joining Technology (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Keyword
- microstructures
- electrodeposition
- morphology evolution
- Li metal anode
- nucleation
Publication and Content Type
- art (subject category)
- ref (subject category)
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Jiao, Xingxing
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Wang, Yongjing
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Kapitanova, Oles ...
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Xu, Xieyu
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Volkov, Valentyn ...
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Liu, Yangyang
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Song, Zhongxiao
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Matic, Aleksanda ...
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Xiong, Shizhao, ...
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Physical Chemist ...
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- ENGINEERING AND TECHNOLOGY
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ENGINEERING AND ...
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and Materials Engine ...
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and Manufacturing Su ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Materials Chemis ...
- Articles in the publication
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Energy Storage M ...
- By the university
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Chalmers University of Technology