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  • Yuan, NingStockholms universitet,Swedish University of Agricultural Sciences,Sveriges lantbruksuniversitet,Institutionen för Molekylära vetenskaper,Department of Molecular Sciences,Stockholm University,Institutionen för material- och miljökemi (MMK),Swedish University of Agricultural Sciences, Sweden (author)

Insights into Functionalization of Metal-Organic Frameworks Using In Situ NMR Spectroscopy

  • Article/chapterEnglish2018

Publisher, publication year, extent ...

  • 2018-12-03
  • Springer Science and Business Media LLC,2018
  • electronicrdacarrier

Numbers

  • LIBRIS-ID:oai:research.chalmers.se:b21db464-a868-4454-a430-aace4567c38f
  • https://doi.org/10.1038/s41598-018-35842-1DOI
  • https://research.chalmers.se/publication/506951URI
  • https://res.slu.se/id/publ/97279URI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-163556URI

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  • Language:English
  • Summary in:English

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  • Subject category:art swepub-publicationtype
  • Subject category:ref swepub-contenttype

Notes

  • Postsynthetic reactions of metal-organic frameworks (MOFs) are versatile tools for producing functional materials, but the methods of evaluating these reactions are cumbersome and destructive. Here we demonstrate and validate the use of in situ NMR spectroscopy of species in the liquid state to examine solvent-assisted ligand exchange (SALE) and postsynthetic modification (PSM) reactions of metal-organic frameworks. This technique allows functionalization to be monitored over time without decomposing the product for analysis, which simplifies reaction screening. In the case of SALE, both the added ligand and the ligand leaving the framework can be observed. We demonstrate this in situ method by examining SALE and PSM reactions of the robust zirconium MOF UiO-67 as well as SALE with the aluminum MOF DUT-5. In situ NMR spectroscopy provided insights into the reactions studied, and we expect that future studies using this method will permit the examination of a variety of MOF–solute reactions.

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  • Church, Tamara L.Stockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)tchur (author)
  • Brandt, Erik G.Stockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)ebran (author)
  • Hedin, NiklasStockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)nhedi (author)
  • Zou, XiaodongStockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)xzou (author)
  • Bernin, Diana,1979Stockholms universitet,Institutionen för material- och miljökemi (MMK),Chalmers University, Sweden(Swepub:cth)dianab (author)
  • Sveriges lantbruksuniversitetInstitutionen för Molekylära vetenskaper (creator_code:org_t)
  • Sveriges lantbruksuniversitet

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  • In:Scientific Reports: Springer Science and Business Media LLC8:12045-23222045-2322

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