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1D and 2D FeII Azid...
1D and 2D FeII Azide Coordination Polymers with Ferromagnetic Canting
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Abu-Youssef, Morsy A.M. (author)
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- Langer, Vratislav, 1949 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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Luneau, Dominique (author)
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Shams, Eman (author)
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Goher, Mohamed A. S. (author)
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- Öhrström, Lars, 1963 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- 2007-12-19
- 2008
- English.
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In: European Journal of Inorganic Chemistry. - : Wiley. - 1434-1948 .- 1099-0682. ; 2008:1, s. 112-118
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http://dx.doi.org/10...
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https://research.cha...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The two compounds [FeII(pyridine)2(N3)2(H2O)] (1) and [FeII(4-acetylpyridine)2(N3)2] (2) were prepared. The X-ray crystal structures show end-to-end (EE) bridging azides in both cases with a 1D Fe-NNN-Fe chain for 1 and a 2D Fe-NNN-Fe net in 2. Both compounds show similar magnetic behaviour where the high-temperature data are consistent with antiferromagnetic couplings and the low-temperature data indicate ferrimagnetic ordering based on spin canting at 20 and 45 K. Compound 2 also shows a hysteresis loop. These findings are compared to the related 3D coordination polymer [Fe(N3)2(4,4'-bipyridine)]. According to network analyses the latter compound was shown to contain the new uninodal six-connected-network topology (510 · 64 · 7)-jsm.
Subject headings
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
Keyword
- coordination polymer
- ferromagnetism
- X-ray structure analysis
Publication and Content Type
- art (subject category)
- ref (subject category)
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