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- Axelsson, Anton,1991Chalmers tekniska högskola,Chalmers University of Technology (author)
Asymmetric aerobic oxidative NHC-catalysed synthesis of dihydropyranones utilising a system of electron transfer mediators
- Article/chapterEnglish2016
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- 2016
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- LIBRIS-ID:oai:research.chalmers.se:c1a46855-84a3-412e-be97-bd04e54aea7e
- https://doi.org/10.1039/C6CC06060ADOI
- https://research.chalmers.se/publication/242129URI
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- Language:English
- Summary in:English
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- In the context of green chemistry, the replacement of high molecular weight stoichiometric oxidants with O2 is most desirable but difficult. Here, we report the asymmetric aerobic oxidative synthesis of dihydropyranones. The oxidation is aided by a system of electron transfer mediators and is selective toward the homoenolate. The dihydropyranones can be isolated in high to excellent yields, with high ee (up to 95%).
Subject headings and genre
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- NATURVETENSKAP Kemi Organisk kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Organic Chemistry hsv//eng
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- Hammarvid, Emmelie,1991Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)emmeha (author)
- Ta, Linda,1989Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)lindat (author)
- Sundén, Henrik,1978Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)sundenh (author)
- Chalmers tekniska högskola (creator_code:org_t)
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- In:Chemical Communications52:77, s. 11571-115741364-548X1359-7345
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