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Studies on an ester...
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Lundberg, Dan,1975Chalmers tekniska högskola,Chalmers University of Technology
(författare)
Studies on an ester-modified cationic amphiphile in aqueous systems: Behavior of binary solutions and ternary mixtures with conventional surfactants
- Artikel/kapitelEngelska2007
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LIBRIS-ID:oai:research.chalmers.se:cbf2ede5-f388-4a3e-a22b-06e62ff56209
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https://research.chalmers.se/publication/80913URI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:art swepub-publicationtype
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Ämneskategori:ref swepub-contenttype
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The aqueous behavior of an ester-modified cationic amphiphile with the molecular structure CH3CH2O(C=O)(CH2)(6)(C=O)O(CH2)sN+(CH3)(3)Br-, in the following referred to as A, has been investigated. Systems with A as the only solute, as well as different aqueous mixtures with conventional cationic surfactants, primarily dodecyltrimethylammonium bromide (DTAB), were included in the study. Isotropic solution samples were characterized using H-1 NMR, C-13 NMR, NMR diffusometry, and conductivity measurements, whereas liquid crystalline samples were investigated by optical polarization microscopy and small-angle X-ray diffraction. The results are compared to the behavior of the binary system of DTAB and water. A does not exhibit a typical surfactant behavior. When it is present as the only solute in a binary aqueous system, it forms neither conventional micelles nor liquid crystalline phases. However; there is clear evidence that it assembles with lower cooperativity into loose clusters at concentrations above 25-30 mM. When A is mixed with DTAB in solution, the two amphiphiles form mixed assemblies, the structure of which varies with the total amphiphile concentration. In concentrated mixtures with alkyltrimethylammonium surfactants, A can participate in hexagonal liquid crystalline phases even when it constitutes a significant fraction of the total amphiphile content.
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Unga, Johan,1976Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)unga
(författare)
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Galloway, A. L.
(författare)
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Menger, F. M.
(författare)
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Chalmers tekniska högskola
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Langmuir23:23, s. 11434-114421520-58270743-7463
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Langmuir
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