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High-pressure dyspr...
High-pressure dysprosium carbides containing carbon dimers, trimers, chains, and ribbons
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- Akbar, Fariia Iasmin (author)
- Univ Bayreuth, Germany
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- Aslandukova, Alena (author)
- Univ Bayreuth, Germany
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- Yin, Yuqing (author)
- Linköpings universitet,Teoretisk Fysik,Tekniska fakulteten,Univ Bayreuth, Germany
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- Aslandukov, Andrey (author)
- Univ Bayreuth, Germany
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- Laniel, Dominique (author)
- Univ Edinburgh, Scotland
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- Bykova, Elena (author)
- Goethe Univ Frankfurt, Germany
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- Bykov, Maxim (author)
- Goethe Univ Frankfurt, Germany
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- Bright, Eleanor Lawrence (author)
- European Synchrotron Radiat Facil, France
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- Wright, Jonathan (author)
- European Synchrotron Radiat Facil, France
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- Comboni, Davide (author)
- European Synchrotron Radiat Facil, France
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- Hanfland, Michael (author)
- European Synchrotron Radiat Facil, France
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- Dubrovinskaia, Natalia (author)
- Linköpings universitet,Teoretisk Fysik,Tekniska fakulteten,Univ Bayreuth, Germany
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- Dubrovinsky, Leonid (author)
- Univ Bayreuth, Germany
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(creator_code:org_t)
- PERGAMON-ELSEVIER SCIENCE LTD, 2024
- 2024
- English.
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In: Carbon. - : PERGAMON-ELSEVIER SCIENCE LTD. - 0008-6223 .- 1873-3891. ; 228
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- Exploring the chemistry of materials at high pressure leads to discoveries of previously unknown compounds and phenomena. Here chemical reactions between elemental dysprosium and carbon were studied in laser-heated diamond anvil cells at pressures up to 95 GPa and temperatures of similar to 2800 K. In situ single-crystal synchrotron X-ray diffraction (SCXRD) analysis of the reaction products revealed the formation of novel dysprosium carbides, gamma-DyC2, Dy5C9, and gamma-Dy4C5, along with previously reported Dy3C2 and Dy4C3 . The crystal structures of gamma-DyC (2) and Dy (5) C (9) feature infinite flat carbon polyacene-like ribbons and cis-polyacetylene-type chains, respectively. In the structure of gamma-Dy4C5, carbon atoms form dimers and non-linear trimers. Dy3C2 contains ethanide-type carbon dumbbells, and Dy4C3 is methanide featuring single carbon atoms. Density functional theory calculations reproduce well the crystal structures of high-pressure dysprosium carbides and reveal conjugated pi-electron systems in novel infinite carbon polyanions. This work demonstrates that complex carbon homoatomic species previously unknown in organic chemistry can be synthesized at high pressures by direct reactions of carbon with metals.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Keyword
- High-pressure; Diamond anvil cell; Rare-earth carbides; Carbides; Rare-earth elements; Dysprosium carbide
Publication and Content Type
- ref (subject category)
- art (subject category)
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Carbon
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- By the author/editor
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Akbar, Fariia Ia ...
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Aslandukova, Ale ...
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Yin, Yuqing
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Aslandukov, Andr ...
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Laniel, Dominiqu ...
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Bykova, Elena
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Bykov, Maxim
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Bright, Eleanor ...
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Wright, Jonathan
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Comboni, Davide
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Hanfland, Michae ...
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Dubrovinskaia, N ...
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Dubrovinsky, Leo ...
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Inorganic Chemis ...
- Articles in the publication
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Carbon
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Linköping University