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Ultrafast charge transfer and atomic orbital polarization

Deppe, M. (author)
Foehlisch, A. (author)
Hennies, Franz (author)
Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory
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Sanchez-Portal, D. (author)
Echenique, P. M. (author)
Wurth, W. (author)
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 (creator_code:org_t)
AIP Publishing, 2007
2007
English.
In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 127:17
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The role of orbital polarization for ultrafast charge transfer between an atomic adsorbate and a substrate is explored. Core hole clock spectroscopy with linearly polarized x-ray radiation allows to selectively excite adsorbate resonance states with defined spatial orientation relative to the substrate surface. For c(4x2)S/Ru(0001) the charge transfer times between the sulfur 2s(-1)3p(*+1) antibonding resonance and the ruthenium substrate have been studied, with the 2s electron excited into the 3p(perpendicular to)(*) state along the surface normal and the 3p(parallel to)(*) state in the surface plane. The charge transfer times are determined as 0.18 +/- 0.07 and 0.84 +/- 0.23 fs, respectively. This variation is the direct consequence of the different adsorbate-substrate orbital overlap.

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NATURVETENSKAP  -- Fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

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Deppe, M.
Foehlisch, A.
Hennies, Franz
Sanchez-Portal, ...
Echenique, P. M.
Wurth, W.
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NATURAL SCIENCES
NATURAL SCIENCES
and Physical Science ...
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Journal of Chemi ...
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