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WFRF:(Venvik Hild J.)
 

Sökning: WFRF:(Venvik Hild J.) > The effect of aeros...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003636naa a2200433 4500
001oai:DiVA.org:lnu-82440
003SwePub
008190506s2019 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:lnu:diva-824402 URI
024a https://doi.org/10.1007/s11144-019-01578-w2 DOI
040 a (SwePub)lnu
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Gavrilovic, Lubisau Norwegian University of Science and Technology, Norway4 aut
2451 0a The effect of aerosol-deposited ash components on a cobalt-based Fischer–Tropsch catalyst
264 c 2019-04-25
264 1b Springer,c 2019
338 a print2 rdacarrier
520 a The effect of ash salts on Co-based Fisher–Tropsch catalysts was studied using an aerosol deposition technique. The major elements in the ash were found to be K, S and Cl. The ash was deposited on a calcined catalyst as dry particles with an average diameter of approx. 350 nm. The loading of ash particles was varied by varying the time of exposure to the particles in a gas stream. Catalyst characterization did not reveal significant differences in cobalt dispersion, reducibility, surface area, pore size, or pore volume between the reference and the catalysts with ash particles deposited. Activity measurements showed that following a short exposure to the mixed ash salts (30 min), there were no significant loss of activity, but a minor change in selectivity of the catalyst . Extended exposure (60 min) led to some activity loss and changes in selectivity. However, extending the exposure time and thus the amount deposited as evidenced by elemental analysis did not lead to a further drop in activity. This behavior is different from that observed with pure potassium salts, and is suggested to be related to the larger size of the aerosol particles deposited. The large aerosol particles used here were probably not penetrating the catalyst bed, and to some extent formed an external layer on the catalyst bed. The ash salts are therefore not able to penetrate to the pore structure and reach the Co active centers, but are mixed with the catalyst and detected in the elemental analysis.
650 7a TEKNIK OCH TEKNOLOGIERx Kemiteknikx Kemiska processer0 (SwePub)204012 hsv//swe
650 7a ENGINEERING AND TECHNOLOGYx Chemical Engineeringx Chemical Process Engineering0 (SwePub)204012 hsv//eng
653 a Fischer-Tropsch
653 a cobalt
653 a ash salts
653 a Analytisk kemi
653 a Analytical Chemistry
700a Brandin, Jan,d 1958-u Linnéuniversitetet,Institutionen för byggd miljö och energiteknik (BET)4 aut0 (Swepub:lnu)jbrbie
700a Holmen, Andersu Norwegian University of Science and Technology, Norway4 aut
700a Venvik, Hild J.u Norwegian University of Science and Technology, Norway4 aut
700a Myrstad, Runeu SINTEF Industry, Norway4 aut
700a Blekkan, Edd A.u Norwegian University of Science and Technology, Norway4 aut
710a Norwegian University of Science and Technology, Norwayb Institutionen för byggd miljö och energiteknik (BET)4 org
773t Reaction Kinetics, Mechanisms and Catalysisd : Springerg 127:1, s. 231-240q 127:1<231-240x 1878-5190x 1878-5204
856u https://rdcu.be/bCT0Hy Fulltext (read only)
856u https://ntnuopen.ntnu.no/ntnu-xmlui/bitstream/11250/2633477/4/Gavrilovic.pdf
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:lnu:diva-82440
8564 8u https://doi.org/10.1007/s11144-019-01578-w

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