WFRF:(Xu Licheng)
Search: WFRF:(Xu Licheng) > (2005-2009) > Isolated Seven-Coor...
- 1 of 8
- Previous record
- Next record
- To hitlist
Isolated Seven-Coordinate Ru(IV) Dimer Complex with HOHOH (-) Bridging Ligand as an Intermediate for Catalytic Water Oxidation
-
- Duan, Lele (author)
- KTH,Organisk kemi
-
- Fischer, Andreas (author)
- KTH,Oorganisk kemi
-
- Xu, Yunhua (author)
- KTH,Organisk kemi
- show more...
- show less...
- (creator_code:org_t)
- 2009-07-14
- 2009
- English.
- In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 131:30, s. 10397-
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- With the inspiration from an oxygen evolving complex (OEC) in Photosystern II (PSII), a mononuclear Ru(II) complex with a tetradentate ligand containing two carboxylate groups has been synthesized and structurally characterized. This Ru(II) complex showed efficient catalytic properties toward water oxidation by the chemical oxidant cerium(IV) ammonium nitrate. During the process of catalytic water oxidation, Ru(III) and Ru(IV) species have been successfully isolated as intermediates. To our surprise, X-ray crystallography together with HR-MS revealed that the Ru(IV) species is a seven-coordinate Ru(IV) dimer complex containing a [HOHOH](-) bridging ligand. This bridging ligand has a short O center dot center dot center dot O distance and is hydrogen bonded to two water molecules. The discovery of this very uncommon seven-coordinate Ru(IV) dimer together with a hydrogen bonding network may contribute to a deeper understanding of the mechanism for catalytic water oxidation. It will also provide new possibilities for the design of more efficient catalysts for water oxidation, which is the key step for solar energy conversion into hydrogen by tight-driven water splitting, the ultimate challenge in artificial photosynthesis.
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
- Journal of the American Chemical Society (Search for host publication in LIBRIS)
To the university's database
- 1 of 8
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Duan, Lele
- Fischer, Andreas
- Xu, Yunhua
- Sun, Licheng
- Articles in the publication
- Journal of the A ...
- By the university
- Royal Institute of Technology
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
