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High gas tightness ZrO2-added silicate glass sealant with low thermal stress for solid oxide fuel cells

Guo, Mengyuan (author)
China University of Mining and Technology-Beijing
Zhang, Xiaoqiang (author)
Lund University,Lunds universitet,Institutionen för energivetenskaper,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Energy Sciences,Departments at LTH,Faculty of Engineering, LTH,University of St Andrews
Li, Ying (author)
China University of Mining and Technology-Beijing
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Andersson, Martin (author)
Lund University,Lunds universitet,Institutionen för energivetenskaper,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Energy Sciences,Departments at LTH,Faculty of Engineering, LTH
Yang, Zhibin (author)
China University of Mining and Technology-Beijing
Peng, Suping (author)
China University of Mining and Technology-Beijing
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 (creator_code:org_t)
Elsevier BV, 2023
2023
English 9 s.
In: Ceramics International. - : Elsevier BV. - 0272-8842. ; 49:12, s. 19708-19716
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • A low leakage rate sealant of 10 wt% ZrO2-added CaO–K2O–Na2O–BaO silicate glass for SOFC has been studied. The structure of the sealant is stable at high temperatures with leakage rates less than 10−4 sccm∙cm−1, and no crystal except for ZrO2 is found in XRD analysis after heating at 800 °C for 100 h. ZrO2 is distributed in the glass matrix and plays a supporting role in avoiding over-softening at operating temperature. Good compatibility in both oxidizing and reducing atmospheres between the sealant and SUS430 interconnect was proved by SEM at 750 °C for 100 h. A fully coupled 3D Multiphysics button SOFC is constructed for mechanical analyses. The results show that the increase of ZrO2 in the sealant will decrease the stress and displacement in the SOFC. Besides, the width of the sealant also affects the stress value and distribution. The results show that GZ10 is a competitive sealing material compared with other ZrO2-added sealants.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Materialteknik -- Keramteknik (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Materials Engineering -- Ceramics (hsv//eng)

Keyword

Glass sealant
Leakage rate
Solid oxide fuel cell
Thermal expansion coefficient
Thermal stress

Publication and Content Type

art (subject category)
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Guo, Mengyuan
Zhang, Xiaoqiang
Li, Ying
Andersson, Marti ...
Yang, Zhibin
Peng, Suping
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ENGINEERING AND TECHNOLOGY
ENGINEERING AND ...
and Materials Engine ...
and Ceramics
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Ceramics Interna ...
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Lund University

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