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Silver-catalyzed dy...
Abstract
Subject headings
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- A dynamic azomethine ylide system was established using Sc(OTf)(3) and Ag/Taniaphos as catalysts. The system was subsequently kinetically resolved in a tandem 1,3-dipolar cycloaddition process where the silver complex acted as both a reaction catalyst and an external selector, resulting in the formation of an exclusive pyrrolidine product in good yield and enantiopurity.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- Combinatorial Resolution
- Asymmetric-Synthesis
- Azomethine Ylides
- Inhibitors
- Alkaloids
- Transformation
- Indolizidine
- Derivatives
- Complexes
- Chemistry
Publication and Content Type
- ref (subject category)
- art (subject category)
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