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A supramolecular photoswitch constructed by intermolecular hydrogen bond between BTEPy and TTF-COOH

Feng, Yanli (author)
Zhang, Qiong (author)
Tan, Wenjuan (author)
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Zhang, Deqing (author)
Tu, Yaoquan (author)
Ågren, Hans (author)
KTH,Teoretisk kemi
Tian, He (author)
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 (creator_code:org_t)
Elsevier BV, 2008
2008
English.
In: Chemical Physics Letters. - : Elsevier BV. - 0009-2614 .- 1873-4448. ; 455:4-6, s. 256-260
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • A novel supramolecular photoswitch containing bisthienylethene- pyridine (BTEPy) and carboxyl attached tetrathiafluvalene (TTF-COOH) was constructed via intermolecular hydrogen bond. FT-IR spectra, XPS characterizations, H-1 NMR and theoretical calculation were carried out to verify the formation of the intermolecular hydrogen bond. The supramolecular self-assemblies BTEPy 2TTF show good photo-chromic properties. A molecular switch with UV/vis light as inputs and electrochemical signals as outputs was obtained.

Keyword

liquid-crystals
diarylethene
tetrathiafulvalene
switches
fluorescence
bisthienylethene
complexes
oligomers
polymers

Publication and Content Type

ref (subject category)
art (subject category)

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