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Hydrogen-bond induc...
Hydrogen-bond induced surface core-level shift in isonicotinic acid
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O'Shea, J. N. (author)
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Schnadt, J. (author)
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Bruhwiler, P. A. (author)
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Hillesheimer, H. (author)
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Martensson, N. (author)
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Patthey, L. (author)
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Krempasky, J. (author)
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Wang, C. K. (author)
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- Luo, Yi (author)
- KTH,Bioteknologi
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- Ågren, Hans (author)
- KTH,Bioteknologi
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(creator_code:org_t)
- 2001-02-20
- 2001
- English.
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In: Journal of Physical Chemistry B. - : American Chemical Society (ACS). - 1089-5647 .- 1520-6106 .- 1520-5207. ; 105:10, s. 1917-1920
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Intermolecular hydrogen-bonding in thick films of isonicotinic acid evaporated onto rutile TiO2(110) has been investigated with X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). The rate of deposition is found to be a key factor in overcoming the kinetic barriers to extensive hydrogen-bond formation, which, when present, gives rise to large energy shifts between bulk and surface in both the N1s XPS and XAS. The origin of the surface core-level shift is attributed to the presence of non-hydrogen-bonded nitrogen atoms in the surface layer.
Keyword
- molecular-beam deposition
- organic thin-films
- rutile tio2(110)
- spectroscopy
- clusters
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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O'Shea, J. N.
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Schnadt, J.
-
Bruhwiler, P. A.
-
Hillesheimer, H.
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Martensson, N.
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Patthey, L.
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show more...
-
Krempasky, J.
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Wang, C. K.
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Luo, Yi
-
Ågren, Hans
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show less...
- Articles in the publication
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Journal of Physi ...
- By the university
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Royal Institute of Technology