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Csp(3)-H Activation...
Csp(3)-H Activation without Chelation Assistance in an Iridium Pincer Complex Forming Cyclometallated Products
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- Ahlstrand, David A. (author)
- Lund University
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- Polukeev, Alexey V. (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Marcos, Rocio (author)
- KTH Royal Institute of Technology,KTH,Teoretisk kemi och biologi
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- Ahlquist, Mårten S. G., 1979- (author)
- KTH Royal Institute of Technology,KTH,Teoretisk kemi och biologi
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- Wendt, Ola F. (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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(creator_code:org_t)
- 2017-01-16
- 2017
- English.
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In: Chemistry - A European Journal. - : WILEY-V C H VERLAG GMBH. - 0947-6539 .- 1521-3765. ; 23:8, s. 1748-1751
- Related links:
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http://dx.doi.org/10...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://lup.lub.lu.s...
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Abstract
Subject headings
Close
- Cyclometallation of 8-methylquinoline and 2-(dimethylamino)-pyridine in an iridium-based pincer complex is described. The C-H activation of 2-(dimethylamino) pyridine is not chelation assisted, which has not been described before for Csp(3)-H bonds in cyclometallation reactions. The mechanism of the cyclometallation of 2-(dimethylamino) pyridine was studied by DFT calculations and kinetic measurements.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Analytisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Analytical Chemistry (hsv//eng)
Keyword
- cyclometallation
- density functional calculations
- iridium
- pincer complexes
- undirected C-H activation
- cyclometallation
- density functional calculations
- iridium
- pincer complexes
- undirected C−H activation
Publication and Content Type
- ref (subject category)
- art (subject category)
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