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Sökning: id:"swepub:oai:DiVA.org:kth-236893" > Isolation of rare e...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00004026naa a2200637 4500
001oai:DiVA.org:kth-236893
003SwePub
008181212s2016 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-2368932 URI
040 a (SwePub)kth
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a kon2 swepub-publicationtype
100a Alemrajabi, Mahmood,d 1989-u KTH,Kemiteknik4 aut0 (Swepub:kth)u16fu27t
2451 0a Isolation of rare earth element phosphate precipitate in the nitrophosphate process for manufacturing of fertilizer
264 1b Canadian Institute of Mining, Metallurgy and Petroleum,c 2016
338 a print2 rdacarrier
500 a QC 20181212
520 a In the present study, the recovery of rare earth elements (REE) in the nitrophosphate process of fertilizer production is investigated. The apatite has been recovered from iron ore tailings by flotation. After digestion of apatite in concentrated nitric acid, Ca(NO3)2.4H2O is first separated by cooling crystallization and then the REEs are recovered by precipitation. Optimum conditions in these steps have been determined in a previous study. The precipitate mainly consists of CaHPO4.2H2O and REE phosphates. In the present study, selective dissolution and re-precipitation have been studied in order to obtain a precipitate that is more concentrated in REEs. The precipitate was selectively dissolved in nitric and phosphoric acid at different acidities (pH 6 to 0) with the liquid /solid ratio of 100 mL/g. It is shown that most of the CaHPO4.2H2O and other calcium containing compounds will be dissolved at pH 2 while the REE phosphates are not dissolved above a pH of approximately 2. Thus, by partial dissolution of the REE precipitate at pH 2.5 most of the solid calcium phosphates will be dissolved and the remaining solid phase, which is more concentrated in REEs, can be filtered off as a fairly concentrated REE solid mass and the liquor can be recycled back to recover more P nutrients. Alternatively, the REE enriched precipitate was dissolved completely in nitric acid and re-precipitated again by addition of ammonium hydroxide to pH 1.2. A chemical equilibrium software, MEDUSA (Puigdomenech, 2013) has been used to evaluate the experimental results and to estimate the optimum conditions for selectively dissolving the precipitate. 
650 7a NATURVETENSKAPx Geovetenskap och miljövetenskapx Geokemi0 (SwePub)105062 hsv//swe
650 7a NATURAL SCIENCESx Earth and Related Environmental Sciencesx Geochemistry0 (SwePub)105062 hsv//eng
653 a Apatite
653 a Precipitation
653 a REE
653 a Selective dissolution
653 a Ammonium hydroxide
653 a Calcium carbide
653 a Calcium phosphate
653 a Concentration (process)
653 a Dissolution
653 a Fertilizers
653 a Flotation
653 a Heterojunctions
653 a Iron ores
653 a Metal recovery
653 a Nitric acid
653 a Ore tailings
653 a Ore treatment
653 a Phosphates
653 a Rare earth elements
653 a Rare earths
653 a Calcium-containing compounds
653 a Chemical equilibriums
653 a Concentrated nitric acid
653 a Cooling crystallization
653 a Fertilizer production
653 a Optimum conditions
653 a Partial dissolution
653 a Precipitation (chemical)
700a Forsberg, Kerstin,d 1979-u KTH,Kemiteknik4 aut0 (Swepub:kth)u1dfmuzo
700a Korkmaz, Kivancu KTH,Kemiteknik4 aut0 (Swepub:kth)u131kc7h
700a Rasmuson, Åke C.u KTH,Kemiteknik4 aut0 (Swepub:kth)u1w1ulhl
710a KTHb Kemiteknik4 org
773t IMPC 2016 - 28th International Mineral Processing Congressd : Canadian Institute of Mining, Metallurgy and Petroleumz 9781926872292
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-236893

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