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Photodegradation of...
Photodegradation of Organometal Hybrid Perovskite Nanocrystals : Clarifying the Role of Oxygen by Single-Dot Photoluminescence
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- Liu, Lige (författare)
- KTH,Tillämpad fysik,Beijing Inst Technol, Sch Phys, Beijing Key Lab, Nanophoton & Ultrafine Optoelect Syst, 5 South St Zhongguancun, Beijing 100081, Peoples R China
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- Deng, Luogen (författare)
- Beijing Inst Technol, Sch Phys, Beijing Key Lab, Nanophoton & Ultrafine Optoelect Syst, 5 South St Zhongguancun, Beijing 100081, Peoples R China.
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- Huang, Sheng (författare)
- Beijing Inst Technol, Sch Mat Sci & Engn, 5 South St Zhongguancun, Beijing 100081, Peoples R China.
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- Zhang, Pei (författare)
- KTH,Tillämpad fysik,Zhengzhou Univ Light Ind, Sch Elect & Informat Engn, Henan Key Lab Informat Based Elect Appliances, Zhengzhou 450002, Henan, Peoples R China
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- Linnros, Jan, 1953- (författare)
- KTH,Fotonik
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- Zhong, Haizheng (författare)
- Beijing Inst Technol, Sch Mat Sci & Engn, 5 South St Zhongguancun, Beijing 100081, Peoples R China.
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- Sychugov, Ilya (författare)
- KTH,Fotonik
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(creator_code:org_t)
- 2019-02-07
- 2019
- Engelska.
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Ingår i: The Journal of Physical Chemistry Letters. - : AMER CHEMICAL SOC. - 1948-7185. ; 10:4, s. 864-869
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Photostability has been a major issue for perovskite materials. Understanding the photodegradation mechanism and suppressing it are of central importance for applications. By investigating single-dot photoluminescence spectra and the lifetime of MAPbX(3) (MA = CH3NH3+, X = Br, I) nanocrystals with quantum confinement under different conditions, we identified two separate pathways in the photodegradation process. The first is the oxygen-assisted light-induced etching process (photochemistry). The second is the light-driven slow charge-trapping process (photophysics), taking place even in oxygen-free environment. We clarified the role of oxygen in the photodegradation process and show how the photoinduced etching can be successfully suppressed by OSTE polymer, preventing an oxygen-assisted reaction.
Ämnesord
- NATURVETENSKAP -- Fysik -- Annan fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Other Physics Topics (hsv//eng)
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