Search: id:"swepub:oai:DiVA.org:kth-255764" >
Paired Electrocatal...
Paired Electrocatalytic Oxygenation and Hydrogenation of Organic Substrates with Water as the Oxygen and Hydrogen Source
-
- Zhang, Peili (author)
- KTH,Kemi,State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, Dalian, 116024, China
-
- Sheng, Xia (author)
- KTH,Organisk kemi,State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, Dalian, 116024, China
-
- Chen, Xiaoyu (author)
- KTH,Teoretisk kemi och biologi
-
show more...
-
Fang, Zhiyong (author)
-
Jiang, Jian (author)
-
Wang, Mei (author)
-
Li, Fusheng (author)
-
- Fan, Lizhou (author)
- KTH,Kemi
-
- Ren, Yansong, 1988- (author)
- KTH,Kemi
-
- Zhang, Biaobiao (author)
- KTH,Kemi
-
- Timmer, Brian J. J. (author)
- KTH,Organisk kemi
-
- Ahlquist, Mårten S. G., 1979- (author)
- KTH,Teoretisk kemi och biologi
-
- Sun, Licheng, 1962- (author)
- KTH,Organisk kemi,State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT-KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology, Dalian, 116024, China
-
show less...
-
(creator_code:org_t)
- 2019-05-22
- 2019
- English.
-
In: Angewandte Chemie International Edition. - : Wiley-VCH Verlagsgesellschaft. - 1433-7851 .- 1521-3773. ; 58:27, s. 9155-9159
- Related links:
-
https://doi.org/10.1...
-
show more...
-
https://onlinelibrar...
-
https://urn.kb.se/re...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- The use of water as an oxygen and hydrogen source for the paired oxygenation and hydrogenation of organic substrates to produce valuable chemicals is of utmost importance as a means of establishing green chemical syntheses. Inspired by the active Ni3+ intermediates involved in electro-catalytic water oxidation by nickel-based materials, we prepared NiBx as a catalyst and used water as the oxygen source for the oxygenation of various organic compounds. NiBx was further employed as both an anode and a cathode in a paired electrosynthesis cell for the respective oxygenation and hydrogenation of organic compounds, with water as both the oxygen and hydrogen source. Conversion efficiency and selectivity of >= 99% were observed during the oxygenation of 5-hydroxy-methylfurfural to 2,5-furandicarboxylic acid and the simultaneous hydrogenation of p-nitrophenol to p-aminophenol. This paired electrosynthesis cell has also been coupled to a solar cell as a stand-alone reactor in response to sunlight.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- electrochemistry
- green chemical synthesis
- hydrogenation
- oxygenation
- water
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database
- By the author/editor
-
Zhang, Peili
-
Sheng, Xia
-
Chen, Xiaoyu
-
Fang, Zhiyong
-
Jiang, Jian
-
Wang, Mei
-
show more...
-
Li, Fusheng
-
Fan, Lizhou
-
Ren, Yansong, 19 ...
-
Zhang, Biaobiao
-
Timmer, Brian J. ...
-
Ahlquist, Mårten ...
-
Sun, Licheng, 19 ...
-
show less...
- About the subject
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Chemical Science ...
- Articles in the publication
-
Angewandte Chemi ...
- By the university
-
Royal Institute of Technology