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Nanocellulose-Based...
Nanocellulose-Based Hybrid Materials for UV Blocking and Mechanically Robust Barriers
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- Abitbol, Tiffany (author)
- RISE,Material- och ytdesign
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- Ahniyaz, Anwar (author)
- RISE,Material- och ytdesign
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- Alvarez-Asencio, Ruben (author)
- RISE,Material- och ytdesign
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- Fall, Andreas (author)
- RISE,Material- och ytdesign
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- Swerin, Agne (author)
- KTH,Yt- och korrosionsvetenskap,KTH Royal Institute of Technology, Sweden
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(creator_code:org_t)
- 2020-03-10
- 2020
- English.
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In: ACS Applied Bio Materials. - : American Chemical Society (ACS). - 2576-6422. ; 3:4, s. 2245-2254
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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Abstract
Subject headings
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- Nanocellulose (NC)-based hybrid coatings and films containing CeO2 and SiO2 nanoparticles (NPs) to impart UV screening and hardness properties, respectively, were prepared by solvent casting. The NC film-forming component (75 wt % of the overall solids) was composed entirely of cellulose nanocrystals (CNCs) or of CNCs combined with cellulose nanofibrils (CNFs). Zeta potential measurements indicated that the four NP types (CNC, CNF, CeO2, and SiO2) were stably dispersed in water and negatively charged at pH values between 6 and 9. The combination of NPs within this pH range ensured uniform formulations and homogeneous coatings and films, which blocked UV light, the extent of which depended on film thickness and CeO2 NP content, while maintaining good transparency in the visible spectrum (∼80%). The addition of a low amount of CNFs (1%) reduced the film hardness, but this effect was compensated by the addition of SiO2 NPs. Chiral nematic self-assembly was observed in the mixed NC film; however, this ordering was disrupted by the addition of the oxide NPs. The roughness of the hybrid coatings was reduced by the inclusion of oxide NPs into the NC matrix perhaps because the spherical oxide NPs were able to pack into the spaces between cellulose fibrils. We envision these hybrid coatings and films in barrier applications, photovoltaics, cosmetic formulations, such as sunscreens, and for the care and maintenance of wood and glass surfaces, or other surfaces that require a smooth, hard, and transparent finish and protection from UV damage.
Subject headings
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
Keyword
- barrier
- ceria
- coatings
- films
- nanocellulose
- silica
- UV
- UV blocking
- Cellulose
- Cellulose derivatives
- Cellulose nanocrystals
- Cerium oxide
- Hard coatings
- Hardness
- pH
- Self assembly
- Silica nanoparticles
- Silicon
- SiO2 nanoparticles
- Cellulose nanocrystal (CNCs)
- Cellulose nanofibrils (CNFs)
- Cosmetic formulations
- Homogeneous coatings
- Mechanically robust
- Nanoparticle (NPs)
- Uniform formulations
- Zeta potential measurements
- Hybrid materials
Publication and Content Type
- ref (subject category)
- art (subject category)
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