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As a single atom Pd...
As a single atom Pd outperforms Pt as the most active co-catalyst for photocatalytic H-2 evolution
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- Cha, Gihoon (author)
- Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany.
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- Hwang, Imgon (author)
- Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany.
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- Hejazi, Seyedsina (author)
- Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany.;Univ Siegen, Chem & Struct Novel Mat, Paul Bonatz Str 9-11, D-57076 Siegen, Germany.
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- Dobrota, Ana S. (author)
- Univ Belgrade, Fac Phys Chem, Studentski Trg 12-16, Belgrade 11000, Serbia.
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- Pašti, Igor A. (author)
- KTH,Strukturer,Univ Belgrade, Fac Phys Chem, Studentski Trg 12-16, Belgrade 11000, Serbia.;KTH Royal Inst Technol, Sch Ind Engn & Management, Dept Mat Sci & Engn, Brinellvagen 23, S-10044 Stockholm, Sweden.
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- Osuagwu, Benedict (author)
- Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany.
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- Kim, Hyesung (author)
- Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany.
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- Will, Johannes (author)
- Univ Erlangen Nurnberg, Inst Micro & Nanostruct Res & Ctr Nanoanal & Elec, IZNF, Cauerstr 3, D-91058 Erlangen, Germany.
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- Yokosawa, Tadahiro (author)
- Univ Erlangen Nurnberg, Inst Micro & Nanostruct Res & Ctr Nanoanal & Elec, IZNF, Cauerstr 3, D-91058 Erlangen, Germany.
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- Badura, Zdenek (author)
- Reg Ctr Adv Technol & Mat, Slechtitelu 27, Olomouc 78371, Czech Republic.
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- Kment, Stepan (author)
- Reg Ctr Adv Technol & Mat, Slechtitelu 27, Olomouc 78371, Czech Republic.
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- Mohajernia, Shiva (author)
- Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany.;Univ Siegen, Chem & Struct Novel Mat, Paul Bonatz Str 9-11, D-57076 Siegen, Germany.
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- Mazare, Anca (author)
- Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany.
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- Skorodumova, Natalia V. (author)
- Uppsala universitet,KTH,Materialvetenskap,Uppsala Univ, Dept Phys & Astron, Box 516, S-75120 Uppsala, Sweden.,Materialteori,KTH Royal Inst Technol, Sch Ind Engn & Management, Dept Mat Sci & Engn, Brinellvagen 23, S-10044 Stockholm, Sweden.
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- Spiecker, Erdmann (author)
- Univ Erlangen Nurnberg, Inst Micro & Nanostruct Res & Ctr Nanoanal & Elec, IZNF, Cauerstr 3, D-91058 Erlangen, Germany.
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- Schmuki, Patrik (author)
- Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany.;Reg Ctr Adv Technol & Mat, Slechtitelu 27, Olomouc 78371, Czech Republic.;King Abdulaziz Univ, Fac Sci, Dept Chem, POB 80203, Jeddah 21569, Saudi Arabia.
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Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany Univ Erlangen Nurnberg, Inst Surface Sci & Corros WW4 LKO, Dept Mat Sci, Martensstr 7, D-91058 Erlangen, Germany.;Univ Siegen, Chem & Struct Novel Mat, Paul Bonatz Str 9-11, D-57076 Siegen, Germany. (creator_code:org_t)
- Elsevier BV, 2021
- 2021
- English.
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In: ISCIENCE. - : Elsevier BV. - 2589-0042. ; 24:8
- Related links:
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https://doi.org/10.1...
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Abstract
Subject headings
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- Here, we evaluate three different noble metal co-catalysts (Pd, Pt, and Au) that are present as single atoms (SAs) on the classic benchmark photocatalyst, TiO2. To trap the single atoms on the surface, we introduced controlled surface vacancies (Ti3+-Ov) on anatase TiO2 nanosheets by a thermal reduction treatment. After anchoring identical loadings of single atoms of Pd, Pt, and Au, we measure the photocatalytic H-2 generation rate and compare it to the classic nanoparticle co-catalysts on the nanosheets. While nanoparticles yield the well-established the hydrogen evolution reaction activity sequence (Pt > Pd > Au), for the single atom form, Pd radically outperforms Pt and Au. Based on density functional theory (DFT), we ascribe this unusual photocatalytic co-catalyst sequence to the nature of the charge localization on the noble metal SAs embedded in the TiO2 surface.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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ISCIENCE
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- By the author/editor
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Cha, Gihoon
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Hwang, Imgon
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Hejazi, Seyedsin ...
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Dobrota, Ana S.
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Pašti, Igor A.
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Osuagwu, Benedic ...
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show more...
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Kim, Hyesung
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Will, Johannes
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Yokosawa, Tadahi ...
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Badura, Zdenek
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Kment, Stepan
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Mohajernia, Shiv ...
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Mazare, Anca
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Skorodumova, Nat ...
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Spiecker, Erdman ...
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Schmuki, Patrik
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Physical Chemist ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Other Chemistry ...
- Articles in the publication
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ISCIENCE
- By the university
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Royal Institute of Technology
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Uppsala University