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Enantioselective Organocatalytic Hydrophosphination of α,β-Unsaturated Aldehydes
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- Ibrahem, Ismail (author)
- Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University
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- Rios, Ramon (author)
- Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University
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- Vesely, Jan (author)
- Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University
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- (creator_code:org_t)
- Wiley, 2007
- 2007
- English.
- In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 46:24, s. 4507-4510
- Journal article (peer-reviewed)
Abstract
Subject headings
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- Keeping it simple: Optically active phosphine derivatives can be obtained in high yields and in up to 99% ee by using simple chiral amines to catalyze the hydrophosphination of α,β-unsaturated aldehydes (see scheme, green sphere = chiral group). The synthetic utility of this highly chemo- and enantioselective transformation was exemplified by the one-pot asymmetric synthesis of β-phosphine oxide acids.
Subject headings
- MEDICIN OCH HÄLSOVETENSKAP -- Medicinska och farmaceutiska grundvetenskaper -- Andra medicinska och farmaceutiska grundvetenskaper (hsv//swe)
- MEDICAL AND HEALTH SCIENCES -- Basic Medicine -- Other Basic Medicine (hsv//eng)
Keyword
- Aldehydes
- Asymmetric synthesis
- Conjugate addition
- Organocatalysis
- Phosphanes
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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- Ibrahem, Ismail
- Rios, Ramon
- Vesely, Jan
- Hammar, Peter
- Eriksson, Lars
- Himo, Fahmi
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- Córdova, Armando
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