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Nanoscale Organic Ferroelectric Resistive Switches

Khikhlovskyi, Vsevolod (author)
Eindhoven University of Technology, Netherlands; TNO, Netherlands
Wang, Rui (author)
TNO, Netherlands
van Breemen, Albert J. J. M. (author)
TNO, Netherlands
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Gelinck, Gerwin H. (author)
TNO, Netherlands
Janssen, Rene A. J. (author)
Eindhoven University of Technology, Netherlands
Kemerink, Martijn (author)
Department of Applied Physics, Eindhoven University of Technology, Eindhoven, The Netherlands
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 (creator_code:org_t)
2014-02-03
2014
English.
In: The Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 118:6, s. 3305-3312
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Organic ferroelectric resistive switches function by grace of nanoscale phase separation in a blend of a semiconducting and a ferroelectric polymer that is sandwiched between metallic electrodes. In this work, various scanning probe techniques are combined with numerical modeling to unravel their operational mechanism. Resistive switching is shown to result from modulation of the charge injection barrier at the semiconductor-electrode interfaces. The modulation is driven by the stray field of the polarization charges in the ferroelectric phase and consequently is restricted to regions where semiconductor and ferroelectric phases exist in close vicinity. Since each semiconductor domain can individually be switched and read out, a novel, nanoscale memory element is demonstrated. An ultimate information density of similar to 30 Mb/cm(2) is estimated for this bottom-up defined memory device.

Subject headings

NATURVETENSKAP  -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Condensed Matter Physics (hsv//eng)

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