id:"swepub:oai:DiVA.org:liu-153172"
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| Fältnamn | Indikatorer | Metadata |
|---|---|---|
| 000 | 03951naa a2200457 4500 | |
| 001 | oai:DiVA.org:liu-153172 | |
| 003 | SwePub | |
| 008 | 181201s2018 | |||||||||||000 ||eng| | |
| 024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-1531722 URI |
| 024 | 7 | a https://doi.org/10.1103/PhysRevMaterials.2.1144012 DOI |
| 040 | a (SwePub)liu | |
| 041 | a engb eng | |
| 042 | 9 SwePub | |
| 072 | 7 | a ref2 swepub-contenttype |
| 072 | 7 | a art2 swepub-publicationtype |
| 100 | 1 | a Tao, Quanzhengu Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten4 aut0 (Swepub:liu)quata69 |
| 245 | 1 0 | a Rare-earth (RE) nanolaminates Mo4RE4Al7C3 featuring ferromagnetism and mixed-valence states |
| 264 | 1 | b AMER PHYSICAL SOC,c 2018 |
| 338 | a electronic2 rdacarrier | |
| 500 | a Funding Agencies|Knut and Alice Wallenberg (KAW) Foundation through a Fellowship [0358, KAW 2015.0043]; Swedish Research council [642-2013-8020]; Flag-ERA JTC; chair of excellence program of the Nanosciences Foundation (Universite Grenoble-Alpes Foundation); Federation Wallonie-Bruxelles through the Action de Recherche Concertee "3D nanoarchitecturing of 2D crystals" [16/21-077]; European Union [696656]; Belgium FNRS (Flag-ERA) [R. 50.01.18.F]; Fonds de la Recherche Scientifique de Belgique (F.R.S. -FNRS) [2.5020.11]; Linkoping Ultra Electron Microscopy Laboratory | |
| 520 | a Rare-earth-based (RE) nanolaminates have attracted attention recently because of their complicated magnetism and their potential as precursors for strongly correlated two-dimensional materials. In this work, we synthesized a class of nanolaminates with a Mo4RE4Al7C3 chemistry, where RE = Ce or Pr. Powder samples of both phases were characterized with respect to structure and composition. Single crystals of Mo4Ce4Al7C3 were used for magnetization measurements. The crystal structure was investigated by means of x-ray diffraction and scanning transmission electron microscopy. Magnetization analysis reveals a ferromagnetic ground state with a Curie temperature of similar to 10.5 K. X-ray absorption near-edge structure provides experimental evidence that Ce is in a mixed-valence state. X-ray magnetic circular dichroism shows that only the Ce atoms with 4f(1) configuration occupying one of the two possible sites are ferromagnetically coupled, with a saturation moment of similar to 1.2 mu(B) per atom. We thus classify Mo4Ce4Al7C3 as a ferromagnetic, mixed-valence compound. | |
| 650 | 7 | a NATURVETENSKAPx Kemix Oorganisk kemi0 (SwePub)104042 hsv//swe |
| 650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Inorganic Chemistry0 (SwePub)104042 hsv//eng |
| 700 | 1 | a Ouisse, T.u Univ Grenoble Alpes, France4 aut |
| 700 | 1 | a Pinek, D.u Univ Grenoble Alpes, France4 aut |
| 700 | 1 | a Chaix-Pluchery, O.u Univ Grenoble Alpes, France4 aut |
| 700 | 1 | a Wilhelm, F.u ESRF, France4 aut |
| 700 | 1 | a Rogalev, A.u ESRF, France4 aut |
| 700 | 1 | a Opagiste, C.u Univ Grenoble Alpes, France4 aut |
| 700 | 1 | a Jouffret, L.u Inst Chim Clermont Ferrand, France4 aut |
| 700 | 1 | a Champagne, A.u UCLouvain, Belgium4 aut |
| 700 | 1 | a Charlier, J-Cu UCLouvain, Belgium4 aut |
| 700 | 1 | a Lu, Junu Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten4 aut0 (Swepub:liu)junlu07 |
| 700 | 1 | a Hultman, Larsu Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten4 aut0 (Swepub:liu)larhu75 |
| 700 | 1 | a Barsoum, M. W.u Drexel Univ, PA 19104 USA4 aut |
| 700 | 1 | a Rosén, Johannau Linköpings universitet,Tunnfilmsfysik,Tekniska fakulteten4 aut0 (Swepub:liu)johro07 |
| 710 | 2 | a Linköpings universitetb Tunnfilmsfysik4 org |
| 773 | 0 | t Physical Review Materialsd : AMER PHYSICAL SOCg 2:11q 2:11x 2475-9953 |
| 856 | 4 | u https://liu.diva-portal.org/smash/get/diva2:1267317/FULLTEXT01.pdfx primaryx Raw objecty fulltext:print |
| 856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-153172 |
| 856 | 4 8 | u https://doi.org/10.1103/PhysRevMaterials.2.114401 |
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