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Selective purification of bleached spruce TMP process water by induced air flotation (IAF)

Zasadowski, Darius (author)
Mittuniversitetet,Avdelningen för kemiteknik
Strand, Anders (author)
Laboratory of Wood and Paper Chemistry, Åbo Academy University, Porthansgatan 3, 20500 Turku, Finland
Sundberg, Anna (author)
Laboratory of Wood and Paper Chemistry, Åbo Academy University, Porthansgatan 3, 20500 Turku, Finland
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Edlund, Håkan (author)
Mittuniversitetet,Avdelningen för kemiteknik
Norgren, Magnus (author)
Mittuniversitetet,Avdelningen för kemiteknik
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 (creator_code:org_t)
2013-08-10
2014
English.
In: Holzforschung. - : Walter de Gruyter GmbH. - 0018-3830 .- 1437-434X. ; 68:2, s. 157-165
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The environmentally benign closure of water systems in paper mills leads to the problem of accumulation of dissolved and colloidal wood substances (DCS) in process water. Notably, pitch affects the pulp and paper production negatively and increases the demand for additional treatment of the process water. In the present article, the purification of thermomechanical pulping process water from the alkaline peroxide bleaching stage has been investigated, with the induced air flotation (IAF) in focus. The following parameters were considered concerning the IAF efficiency to remove detrimental substances: concentration of cationic foaming agent, pH value, calcium concentration, and temperature. The amounts and characteristics of residual DCS were determined by gas chromatography and turbidity measurements. Residual concentrations of the foaming agent dodecyltrimetylammonium chloride were determined by electrospray ionization mass spectrometry. Up to 90% of pitch was removed, whereas hemicelluloses, which are important in preventing pitch problems, remained in the waters. Up to 70% of the pectic acids accounted for the high cationic demand of the process waters were removed by optimization of the IAF parameters. The presented separation process gives new opportunities to a selective purification of the process waters.

Subject headings

NATURVETENSKAP  -- Kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Keyword

cationic dodecyltrimetylammonium chloride (DoTAC)
cationic foaming agent (DoTAC)
colloidal wood pitch
induced air flotation
mechanical pulp
pectic acids
peroxide bleaching

Publication and Content Type

ref (subject category)
art (subject category)

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Zasadowski, Dari ...
Strand, Anders
Sundberg, Anna
Edlund, Håkan
Norgren, Magnus
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NATURAL SCIENCES
NATURAL SCIENCES
and Chemical Science ...
Articles in the publication
Holzforschung
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Mid Sweden University

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