Sökning: id:"swepub:oai:DiVA.org:miun-3720" > Enantiomerically en...
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000 | 03123naa a2200469 4500 | |
001 | oai:DiVA.org:miun-3720 | |
003 | SwePub | |
008 | 080930s2006 | |||||||||||000 ||eng| | |
009 | oai:DiVA.org:kth-8992 | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:miun:diva-37202 URI |
024 | 7 | a https://doi.org/10.1016/j.tetasy.2005.12.0122 DOI |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-89922 URI |
040 | a (SwePub)miund (SwePub)kth | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Isaksson, Danu Mittuniversitetet,Institutionen för naturvetenskap (-2008)4 aut0 (Swepub:kth)u1xwn69o |
245 | 1 0 | a Enantiomerically enriched cryptone by lipase catalysed kinetic resolution |
264 | 1 | b Elsevier BV,c 2006 |
338 | a print2 rdacarrier | |
500 | a Corrigendum to "Enantiomerically enriched cryptone by lipase catalysed kinetic resolution". [Tetrahedron: Asymmetry 17 (2006) 275] (DOI:10.1016/j.tetasy.2005.12.012)Tetrahedron Asymmetry Volume 17, Issue 8, 18 April 2006, Page 1318DOI: 10.1016/j.tetasy.2006.04.028ScopusID: 2-s2.0-33646837669 | |
500 | a QC 20100901 Tidigare titel:Enantiomerically enriched cryptone obtained by lipase catalysed resolution. | |
520 | a Thiophenol was added to racemic cryptone (4-isopropyl-2-cyclohexene-1-one) and the resulting 1,4-addition products, cis- and trans-4-isopropyl-3-(phenylsulfanyl)cyclohexanone) were separated and the latter reduced to rac-1,3-cis-1,4-trans-4-isopropyl-3-(phenylsulfanyl)cyclo¬he¬xanol which was subjected to lipase catalysed resolution by acylation catalysed by CAL-B (Candida antarctica lipase B). The remaining alcohol was separated from the produced acetate, which was hydrolysed to the alcohol. The enantiomeric alcohols so obtained were oxidised. The initial products, probably sulfoxidoketones spontaneously decomposed to furnish enantiomerically enriched (R)- and (S)-cryptone with up to 76% and 98% ee, respectively. | |
650 | 7 | a NATURVETENSKAPx Kemi0 (SwePub)1042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciences0 (SwePub)1042 hsv//eng |
650 | 7 | a NATURVETENSKAPx Kemix Organisk kemi0 (SwePub)104052 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Organic Chemistry0 (SwePub)104052 hsv//eng |
653 | a cryptone | |
653 | a resolution | |
653 | a lipase | |
653 | a CAL-B | |
653 | a Chemistry | |
653 | a Kemi | |
653 | a Organic chemistry | |
700 | 1 | a Sjödin, Kristinau Mittuniversitetet,Institutionen för naturvetenskap (-2008)4 aut0 (Swepub:kth)u1kv1imf |
700 | 1 | a Högberg, Hans-Eriku Mittuniversitetet,Institutionen för naturvetenskap (-2008)4 aut0 (Swepub:kth)u17poql9 |
710 | 2 | a Mittuniversitetetb Institutionen för naturvetenskap (-2008)4 org |
773 | 0 | t Tetrahedrond : Elsevier BVg 17:2, s. 275-280q 17:2<275-280x 0957-4166x 1362-511X |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:miun:diva-3720 |
856 | 4 8 | u https://doi.org/10.1016/j.tetasy.2005.12.012 |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-8992 |
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