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Construction of Mesoporous Frameworks with Vanadoborate Clusters

Chen, Hong (author)
Stockholms universitet,Institutionen för material- och miljökemi (MMK),China University of Geosciences, Wuhan
Yu, Zheng-Bao (author)
Bacsik, Zoltan (author)
Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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Zhao, Huishuang (author)
Stockholms universitet,Institutionen för material- och miljökemi (MMK)
Yao, Qingxia (author)
Stockholms universitet,Institutionen för material- och miljökemi (MMK)
Sun, Junliang (author)
Stockholms universitet,Institutionen för material- och miljökemi (MMK),Peking University, China
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 (creator_code:org_t)
2014-03-03
2014
English.
In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 53:14, s. 3608-3611
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • A new porous vanadoborate was synthesized by employing the scale chemistry theory with the vanadoborate cluster V10B28. The twofold interpenetrated lvt network was assembled with zinc-containing elliptical vanadoborate clusters and Zn polyhedra. The single lvt framework contains a three-dimensional 38x38x20 ring channel system with the pore size (24.7x12.7 angstrom) reaching the mesoscale, thus indicating the possibility of constructing 3D ordered mesopores with vanadoborate clusters. The porosity of the SUT-7 structure was confirmed by CO2 adsorption of the as-synthesized materials.

Subject headings

NATURVETENSKAP  -- Kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Keyword

3D frameworks
cluster compounds
CO2 adsorption
mesoporous materials
vanadoborates

Publication and Content Type

ref (subject category)
art (subject category)

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By the author/editor
Chen, Hong
Yu, Zheng-Bao
Bacsik, Zoltan
Zhao, Huishuang
Yao, Qingxia
Sun, Junliang
About the subject
NATURAL SCIENCES
NATURAL SCIENCES
and Chemical Science ...
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Angewandte Chemi ...
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Stockholm University

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