A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores

Feng, Dawei (author)

Wang, Kecheng (author)

Su, Jie (author): Stockholms universitet,Avdelningen för oorganisk kemi och strukturkemi

Liu, Tian-Fu (author)

Park, Jihye (author)

Wei, Zhangwen (author)

Bosch, Mathieu (author)

Yakovenko, Andrey (author)

Zou, Xiaodong (author): Stockholms universitet,Avdelningen för oorganisk kemi och strukturkemi

Zhou, Hong-Cai (author)

(creator_code:org_t)

2014-11-10
2015
English.
In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 54:1, s. 149-154

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Abstract Subject headings

Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8nm and the highest pore volume of 2.8cm(3)g(-1) among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN-777 and different guests can be varied to realize efficient immobilization.

By the author/editor: Feng, Dawei; Wang, Kecheng; Su, Jie; Liu, Tian-Fu; Park, Jihye; Wei, Zhangwen; show more...; Bosch, Mathieu; Yakovenko, Andre ...; Zou, Xiaodong; Zhou, Hong-Cai; show less...

About the subject

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