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A series of isostructural mesoporous metal-organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation
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- Yao, Qingxia (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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- Sun, Junliang (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
- Li, Kuo (author)
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- Royal Society of Chemistry (RSC), 2012
- 2012
- English.
- In: Dalton Transactions. - : Royal Society of Chemistry (RSC). - 1477-9226 .- 1477-9234. ; 41:14, s. 3953-3955
- Journal article (peer-reviewed)
Abstract
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- A series of metal-organic frameworks representing a non-interpenetrated framework analogue of MOF-14 have been synthesized by using two different linkers, 4,4',4 ''-benzene-1,3,5-triyl-benzoic acid (H3BTB) and 4,4'-bipyridine (Bpy). Interestingly, the transition metal ions in the paddle-wheel metal clusters could be exchanged by other transition metal ions via a direct single-crystal to single-crystal transformation. This post-synthesis route can be used for synthesis of isomorphous metal-organic frameworks that cannot be obtained by direct synthesis.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
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- ref (subject category)
- art (subject category)
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- Yao, Qingxia
- Sun, Junliang
- Li, Kuo
- Su, Jie
- Peskov, Maxim V.
- Zou, Xiaodong
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- NATURAL SCIENCES
- NATURAL SCIENCES
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