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Valence-Dependent E...
Valence-Dependent Electrical Conductivity in a 3D Tetrahydroxyquinone-Based Metal-Organic Framework
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Chen, Gan (author)
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Gee, Leland B. (author)
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Xu, Wenqian (author)
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Zhu, Yanbing (author)
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Lezama-Pacheco, Juan S. (author)
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- Huang, Zhehao (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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Li, Zongqi (author)
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Babicz, Jeffrey T. (author)
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Choudhury, Snehashis (author)
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Chang, Ting-Hsiang (author)
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Reed, Evan (author)
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Solomon, Edward (author)
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Bao, Zhenan (author)
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(creator_code:org_t)
- 2020-12-14
- 2020
- English.
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In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 142:51, s. 21243-21248
- Related links:
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https://www.ncbi.nlm...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- Electrically conductive metal-organic frameworks (cMOFs) have become a topic of intense interest in recent years because of their great potential in electrochemical energy storage, electrocatalysis, and sensing applications. Most of the cMOFs reported hitherto are 2D structures, and 3D cMOFs remain rare. Herein we report FeTHQ a 3D cMOF synthesized from tetrahydroxy-1,4-quinone (THQ) and iron(II) sulfate salt. FeTHQexhibited a conductivity of 3.3 +/- 0.55 mS cm(-1) at 300 K, which is high for 3D cMOFs. The conductivity of FeTHQis valence-dependent. A higher conductivity was measured with the as-prepared FeTHQ than with the air-oxidized and sodium naphthalenide-reduced samples.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Chen, Gan
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Gee, Leland B.
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Xu, Wenqian
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Zhu, Yanbing
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Lezama-Pacheco, ...
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Huang, Zhehao
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show more...
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Li, Zongqi
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Babicz, Jeffrey ...
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Choudhury, Sneha ...
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Chang, Ting-Hsia ...
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Reed, Evan
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Solomon, Edward
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Bao, Zhenan
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
- Articles in the publication
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Journal of the A ...
- By the university
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Stockholm University