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Chemoenzymatic Dynamic Kinetic Resolution of Allylic Alcohols : A Highly Enantioselective Route to Acyloin Acetates
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- Bogár, Krisztián (author)
- Stockholms universitet,Institutionen för organisk kemi
- Hoyos Vidal, Pilar (author)
- Alcántara León, Andrés R. (author)
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- (creator_code:org_t)
- 2007-07-21
- 2007
- English.
- In: Organic Letters. - : American Chemical Society (ACS). - 1523-7060 .- 1523-7052. ; 9:17, s. 3401-3404
- Journal article (peer-reviewed)
Abstract
Subject headings
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- Dynamic kinetic resolution (DKR) of a series of sterically hindered allylic alcohols has been conducted with Candida antarctica lipase B (CALB) and ruthenium catalyst 1. The optically pure allylic acetates obtained were subjected to oxidative cleavage to give the corresponding acylated acyloins in high yields without loss of chiral information.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- Organic chemistry
- Organisk kemi
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- ref (subject category)
- art (subject category)
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- Bäckvall, Jan-E.
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- Organic Letters
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- Stockholm University
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