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Dissociative charge...
Abstract
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- Translational spectroscopy coupled with coincidence detection techniques has been used to study the dissociation dynamics of ground state H/D+N-2 products resulting from charge exchange between keV beams of HN2+/DN2+ and cesium. Analysis of the product kinetic energy release suggests that dissociation of HN2 and DN2 proceeds from initial populations in the (2)A '', 2 (2)A ', and 3s Rydberg electronic states of the neutral molecule. Although all three excited electronic states must eventually couple to the 1 (2)A ' ground state of HN2/DN2, the resulting dissociation dynamics exhibit a significant dependence on the initial electronic state. Potential mechanisms are discussed in light of the observed product kinetic energy release distributions.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Keyword
- potential-energy surface
- excited-state topology
- global ab-initio
- theoretical characterization
- electron recombination
- photodissociation dynamics
- unimolecular dissociation
- 3-body dissociation
- sym-triazine
- n2h
- Chemical physics
- Kemisk fysik
Publication and Content Type
- ref (subject category)
- art (subject category)
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